Solution Thermodynamics and Its Application to Aqueous Solutions

Solution Thermodynamics and Its Application to Aqueous Solutions
Author: Yoshikata Koga
Publsiher: Elsevier Science
Total Pages: 526
Release: 2017-04-01
ISBN 10: 9780444636294
ISBN 13: 0444636293
Language: EN, FR, DE, ES & NL

Solution Thermodynamics and Its Application to Aqueous Solutions Book Review:

Solution Thermodynamics and its Application to Aqueous Solutions, Second Edition, introduces a differential approach to solution thermodynamics and applies it to the study of aqueous solutions. This valuable approach reveals the molecular processes in solutions in greater depth than that gained by spectroscopic and other methods. The book clarifies what a hydrophobe, or a hydrophile, and in turn, an amphiphile, does to H2O. By applying the same methodology to ions that have been ranked by the Hofmeister series, the author shows that the kosmotropes are either hydrophobes or hydration centres, and that chaotropes are hydrophiles. This unique approach and important updates make the new edition a "must-have" reference for those active in solution chemistry. Unique differential approach to solution thermodynamics allows for experimental evaluation of the intermolecular interaction Incorporates research findings from over 40 articles published since the previous edition Numerical or graphical evaluation and direct experimental determination of third derivatives, enthalpic and volumetric AL-AL interactions and amphiphiles are new to this edition Features new chapters on spectroscopic study in aqueous solutions as well as environmentally friendly and hostile water aqueous solutions

Solution Thermodynamics and its Application to Aqueous Solutions

Solution Thermodynamics and its Application to Aqueous Solutions
Author: Yoshikata Koga
Publsiher: Elsevier
Total Pages: 310
Release: 2007-11-12
ISBN 10: 9780080551876
ISBN 13: 0080551874
Language: EN, FR, DE, ES & NL

Solution Thermodynamics and its Application to Aqueous Solutions Book Review:

As the title suggests, we introduce a novel differential approach to solution thermodynamics and use it for the study of aqueous solutions. We evaluate the quantities of higher order derivative than the normal thermodynamic functions. We allow these higher derivative data speak for themselves without resorting to any model system. We thus elucidate the molecular processes in solution, (referred to in this book “mixing scheme ), to the depth equal to, if not deeper, than that gained by spectroscopic and other methods. We show that there are three composition regions in aqueous solutions of non-electrolytes, each of which has a qualitatively distinct mixing scheme. The boundary between the adjacent regions is associated with an anomaly in the third derivatives of G. The loci of the anomalies in the temperature-composition field form the line sometimes referred as “Koga line . We then take advantage of the anomaly of a third derivative quantity of 1-propanol in the ternary aqueous solution, 1-propanol – sample species – H2O. We use its induced change as a probe of the effect of a sample species on H2O. In this way, we clarified what a hydrophobe, or a hydrophile, and in turn, an amphiphile, does to H2O. We also apply the same methodology to ions that have been ranked by the Hofmeister series. We show that the kosmotropes (salting out, or stabilizing agents) are either hydrophobes or hydration centres, and that chaotropes (salting in, or destablizing agents) are hydrophiles. A new differential approach to solution thermodynamics A particularly clear elucidation of the mixing schemes in aqueous solutions A clear understandings on the effects of hydrophobes, hydrophiles, and amphiphiles to H2O A clear understandings on the effects of ions on H2O in relation to the Hofmeister effect A new differential approach to studies in muti-component aqueous solutions

Solution Thermodynamics and Its Application to Aqueous Solutions

Solution Thermodynamics and Its Application to Aqueous Solutions
Author: Yoshikata Koga
Publsiher: Elsevier
Total Pages: 444
Release: 2017-03-28
ISBN 10: 0444636307
ISBN 13: 9780444636300
Language: EN, FR, DE, ES & NL

Solution Thermodynamics and Its Application to Aqueous Solutions Book Review:

Solution Thermodynamics and its Application to Aqueous Solutions: A Differential Approach, Second Edition introduces a differential approach to solution thermodynamics, applying it to the study of aqueous solutions. This valuable approach reveals the molecular processes in solutions in greater depth than that gained by spectroscopic and other methods. The book clarifies what a hydrophobe, or a hydrophile, and in turn, an amphiphile, does to H2O. By applying the same methodology to ions that have been ranked by the Hofmeister series, the author shows that the kosmotropes are either hydrophobes or hydration centers, and that chaotropes are hydrophiles. This unique approach and important updates make the new edition a must-have reference for those active in solution chemistry. Unique differential approach to solution thermodynamics allows for experimental evaluation of the intermolecular interaction Incorporates research findings from over 40 articles published since the previous edition Numerical or graphical evaluation and direct experimental determination of third derivatives, enthalpic and volumetric AL-AL interactions and amphiphiles are new to this edition Features new chapters on spectroscopic study in aqueous solutions as well as environmentally friendly and hostile water aqueous solutions

Phase Diagrams and Thermodynamic Modeling of Solutions

Phase Diagrams and Thermodynamic Modeling of Solutions
Author: Arthur D. Pelton
Publsiher: Academic Press
Total Pages: 401
Release: 2018-09-19
ISBN 10: 0128016698
ISBN 13: 9780128016695
Language: EN, FR, DE, ES & NL

Phase Diagrams and Thermodynamic Modeling of Solutions Book Review:

Phase Diagrams and Thermodynamic Modeling of Solutions provides readers with an understanding of thermodynamics and phase equilibria that is required to make full and efficient use of these tools. The book systematically discusses phase diagrams of all types, the thermodynamics behind them, their calculations from thermodynamic databases, and the structural models of solutions used in the development of these databases. Featuring examples from a wide range of systems including metals, salts, ceramics, refractories, and concentrated aqueous solutions, Phase Diagrams and Thermodynamic Modeling of Solutions is a vital resource for researchers and developers in materials science, metallurgy, combustion and energy, corrosion engineering, environmental engineering, geology, glass technology, nuclear engineering, and other fields of inorganic chemical and materials science and engineering. Additionally, experts involved in developing thermodynamic databases will find a comprehensive reference text of current solution models. Presents a rigorous and complete development of thermodynamics for readers who already have a basic understanding of chemical thermodynamics Provides an in-depth understanding of phase equilibria Includes information that can be used as a text for graduate courses on thermodynamics and phase diagrams, or on solution modeling Covers several types of phase diagrams (paraequilibrium, solidus projections, first-melting projections, Scheil diagrams, enthalpy diagrams), and more

Thermodynamics of Dilute Aqueous Solutions

Thermodynamics of Dilute Aqueous Solutions
Author: Marcel Pourbaix
Publsiher: Unknown
Total Pages: 136
Release: 1949
ISBN 10:
ISBN 13: WISC:89089669964
Language: EN, FR, DE, ES & NL

Thermodynamics of Dilute Aqueous Solutions Book Review:

Water in Crystalline Hydrates Aqueous Solutions of Simple Nonelectrolytes

Water in Crystalline Hydrates Aqueous Solutions of Simple Nonelectrolytes
Author: Felix Franks
Publsiher: Springer Science & Business Media
Total Pages: 684
Release: 2013-04-18
ISBN 10: 147576958X
ISBN 13: 9781475769586
Language: EN, FR, DE, ES & NL

Water in Crystalline Hydrates Aqueous Solutions of Simple Nonelectrolytes Book Review:

vi the information collected and discussed in this volume may help toward the achievement of such an objective. I should like to express my debt of gratitude to the authors who have contributed to this volume. Editing a work of this nature can strain long established personal relationships and I thank my various colleagues for bearing with me and responding (sooner or later) to one or several letters or telephone calls. My special thanks once again go to Mrs. Joyce Johnson, who bore the main brunt of this seemingly endless correspondence and without whose help the editorial and referencing work would have taken several years. F. FRANKS Biophysics Division Unilever Research Laboratory Colworth/ Welwyn Colworth House, Sharnbrook, Bedford January, 1973 Contents Contents of Volume 1 ............................. . . . . . .. . . .. xv Contents of Volume 3 ........................ '. . . . . . . . . . . . xvi . . . . Contents of Volume 4 . . . . . . . . . . . . . . . . . . . . . . . . .. . . . xvii . . . . . . . . . . . Chapter 1 The Solvent Properties of Water F. Franks 1. Water, the Universal Solvent-the Study of Aqueous Solutions 2. Aqueous Solutions of Nonelectrolytes ................. . 5 2.1. Apolar Solutes ................................. . 6 2.2. Polar Solutes .................................. . 19 2.3. Ionic Solutes Containing Alkyl Residues-"Apolar Electrolytes" ................................... . 38 3. Aqueous Solutions of Electrolytes .................... . 42 3.1. Single Ion Properties ............................ . 42 3.2. Ion-Water Interactions ......................... . 43 3.3. Interionic Effects ............................... . 47 4. Complex Aqueous Mixtures 48 Chapter 2 Water in Stoichiometric Hydrates M. Falk and O. Knop 1. Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55 . . . . . . . . . . . . . 2. Symmetry and Types of Environment of the H0 Molecule 2 in Crystals .......................................... 57 vii Contents viii 2.1. Site Symmetry. . . . . . . . . . . . . . . . . . . . . . . . . 57 . . . . . . . . . .

Thermodynamics of Aqueous Systems with Industrial Applications

Thermodynamics of Aqueous Systems with Industrial Applications
Author: Stephen A. Newman
Publsiher: Unknown
Total Pages: 129
Release: 1980
ISBN 10:
ISBN 13: STANFORD:36105031589232
Language: EN, FR, DE, ES & NL

Thermodynamics of Aqueous Systems with Industrial Applications Book Review:

Molecular Theory of Water and Aqueous Solutions

Molecular Theory of Water and Aqueous Solutions
Author: Arieh Ben-Naim
Publsiher: World Scientific Publishing Company Incorporated
Total Pages: 629
Release: 2009
ISBN 10:
ISBN 13: CHI:091934959
Language: EN, FR, DE, ES & NL

Molecular Theory of Water and Aqueous Solutions Book Review:

The aim of this book is to explain the unusual properties of both pure liquid water and simple aqueous solutions, in terms of the properties of single molecules and interactions among small numbers of water molecules. It is mostly the result of the author's own research spanning over 40 years in the field of aqueous solutions. An understanding of the properties of liquid water is a prelude to the understanding of the role of water in biological systems and for the evolvement of life. The book is targeted at anyone who is interested in the outstanding properties of water and its role in biological systems. It is addressed to both students and researchers in chemistry, physics and biology.

Thermodynamics of Aqueous Solutions of Quaternary Ammonium Salts

Thermodynamics of Aqueous Solutions of Quaternary Ammonium Salts
Author: Wen-Yang Wen
Publsiher: Unknown
Total Pages: 27
Release: 1965
ISBN 10:
ISBN 13: UOM:39015078499681
Language: EN, FR, DE, ES & NL

Thermodynamics of Aqueous Solutions of Quaternary Ammonium Salts Book Review:

Handbook of Aqueous Electrolyte Thermodynamics

Handbook of Aqueous Electrolyte Thermodynamics
Author: Joseph F. Zemaitis, Jr.,Diane M. Clark,Marshall Rafal,Noel C. Scrivner
Publsiher: John Wiley & Sons
Total Pages: 878
Release: 2010-09-16
ISBN 10: 0470938404
ISBN 13: 9780470938409
Language: EN, FR, DE, ES & NL

Handbook of Aqueous Electrolyte Thermodynamics Book Review:

Expertise in electrolyte systems has become increasingly important in traditional CPI operations, as well as in oil/gas exploration and production. This book is the source for predicting electrolyte systems behavior, an indispensable "do-it-yourself" guide, with a blueprint for formulating predictive mathematical electrolyte models, recommended tabular values to use in these models, and annotated bibliographies. The final chapter is a general recipe for formulating complete predictive models for electrolytes, along with a series of worked illustrative examples. It can serve as a useful research and application tool for the practicing process engineer, and as a textbook for the chemical engineering student.

Molecular Thermodynamics of Proteins in Aqueous Solutions of Concentrated Electrolyte

Molecular Thermodynamics of Proteins in Aqueous Solutions of Concentrated Electrolyte
Author: Robin Andrew Curtis
Publsiher: Unknown
Total Pages: 524
Release: 2000
ISBN 10:
ISBN 13: UCAL:C3446311
Language: EN, FR, DE, ES & NL

Molecular Thermodynamics of Proteins in Aqueous Solutions of Concentrated Electrolyte Book Review:

Thermodynamics of Solution of Gases in Aqueous Solutions

Thermodynamics of Solution of Gases in Aqueous Solutions
Author: Arieh Ben-Naim
Publsiher: Unknown
Total Pages: 329
Release: 1964
ISBN 10:
ISBN 13: OCLC:741922847
Language: EN, FR, DE, ES & NL

Thermodynamics of Solution of Gases in Aqueous Solutions Book Review:

AIChE Symposium Series

AIChE Symposium Series
Author: Anonim
Publsiher: Unknown
Total Pages: 132
Release: 1984
ISBN 10:
ISBN 13: UVA:X000899031
Language: EN, FR, DE, ES & NL

AIChE Symposium Series Book Review:

Petroleum Abstracts

Petroleum Abstracts
Author: Anonim
Publsiher: Unknown
Total Pages: 329
Release: 1990-10
ISBN 10:
ISBN 13: STANFORD:36105006127331
Language: EN, FR, DE, ES & NL

Petroleum Abstracts Book Review:

Dissertation Abstracts International

Dissertation Abstracts International
Author: Anonim
Publsiher: Unknown
Total Pages: 329
Release: 1970
ISBN 10:
ISBN 13: MINN:31951D00323040V
Language: EN, FR, DE, ES & NL

Dissertation Abstracts International Book Review:

Kinetics and Analysis of Aspartame Decomposition Mechanisms in Aqueous Solutions Using Multiresponse Methods

Kinetics and Analysis of Aspartame Decomposition Mechanisms in Aqueous Solutions Using Multiresponse Methods
Author: Jeffrey Allen Stamp
Publsiher: Unknown
Total Pages: 329
Release: 1990
ISBN 10:
ISBN 13: MINN:31951D00569153M
Language: EN, FR, DE, ES & NL

Kinetics and Analysis of Aspartame Decomposition Mechanisms in Aqueous Solutions Using Multiresponse Methods Book Review:

Thermodynamics of Seawater as a Multicomponent Electrolyte Solution

Thermodynamics of Seawater as a Multicomponent Electrolyte Solution
Author: J. V. Leyendekkers
Publsiher: Unknown
Total Pages: 329
Release: 1976
ISBN 10: 9780824764869
ISBN 13: 0824764862
Language: EN, FR, DE, ES & NL

Thermodynamics of Seawater as a Multicomponent Electrolyte Solution Book Review:

Equilibrium Properties of Aqueous Solutions of Single Strong Electrolytes

Equilibrium Properties of Aqueous Solutions of Single Strong Electrolytes
Author: Edward Armand Guggenheim,Robert Harold Stokes
Publsiher: Pergamon
Total Pages: 148
Release: 1969
ISBN 10:
ISBN 13: UCSD:31822007887474
Language: EN, FR, DE, ES & NL

Equilibrium Properties of Aqueous Solutions of Single Strong Electrolytes Book Review:

Thermodynamics

Thermodynamics
Author: James Riddick Partington
Publsiher: Unknown
Total Pages: 263
Release: 1950
ISBN 10:
ISBN 13: WISC:89089669832
Language: EN, FR, DE, ES & NL

Thermodynamics Book Review:

Unit Processes of Extractive Metallurgy

Unit Processes of Extractive Metallurgy
Author: Robert D. Pehlke
Publsiher: Elsevier Publishing Company
Total Pages: 396
Release: 1973
ISBN 10:
ISBN 13: UOM:39015004526920
Language: EN, FR, DE, ES & NL

Unit Processes of Extractive Metallurgy Book Review: