Polymer Foams Handbook

From crash helmets to packaging, this is the complete guide to understanding, selecting, processing and working with polymer foams.

This Handbook reviews the chemistry, manufacturing methods, properties and applications of the synthetic polymer foams used in most applications. In addition, a chapter is included on the fundamental principles, which apply to all polymer foams. There is also a chapter on the blowing agents used to expand polymers and a chapter is on microcellular foams - a relatively new development where applications are still being explored.

The use of polymer foams is extremely widespread. Indeed, it is hard to think of any industries where polymer foams do not have a part to play. They can be found for example in sports and leisure products, in military applications, in vehicles, in aircraft, and in the home. Most people will encounter polymer foams every day in one form or another, whether it be in furniture, in packaging, in their car, in refrigerator insulation, or in some other common application. Although naturally occurring polymer foams have been known for a long time, (e.g., sponges, cork), synthetic polymer foams have only been introduced to the market over the last fifty years or so. The development of a new polymer has usually been quickly followed by its production in an expanded or foam form owing to the unique and useful properties, which can be realised in the expanded state. This handbook reviews the chemistry, manufacturing methods, properties and applications of the synthetic polymer foams used in most applications. In addition, a chapter is included on the fundamental principles, which apply to all polymer foams. There is also a chapter on the blowing agents used to expand polymers, blowing agents having undergone considerable change and development in recent years in order to meet the requirements of the Montreal Protocol in relation to the reduction and elimination of chloroflurocarbons (CFC) and other ozone depleting agents. A chapter is also included on microcellular foams - a relatively new development where applications are still being explored. Most chapters have references to facilitate further exploration of the topics. The chapters are all written by experts in the field. This book will be of interest to those just embarking upon an exploration of the subject of foams, whether in industry or academia. But this will be equally useful to those already working in the field, who need to know about different types of foam.

This book is intended to be a source of practical information on all types of plastic foams (cellular plastics) in use, including the new structural plastic foams. Elastomer (rubber-like) foams are also considered. The book is intended primarily for those who require a non-theoretical, authoritative, easy-to-use handbook in the subject area. It should be of value to materials engineers, plastics fabricators, chemists, chemical engineers and students. Recognized authorities have written several chapters and parts of chapters in their fields of expertise. The book is organized in such a way that information on a desired subject can be found rapidly. An unusual feature is a comprehensive listing of all known standardization documents (test methods, practices, and specifications), including some international standards. Each document includes a brief description of its contents.

Handbook of Foaming and Blowing Agents provides useful guidance to assist practitioners in the more efficient and effective selection of foaming methods and blowing agents. The book focuses on the selection of additives for a diverse range of foaming processes, which can be enhanced using modern chemical means to improve product quality, speed up the process, and broaden the range of products that can be produced using foaming technology. Foamed polymers have many beneficial properties, including lower density, high heat and sound insulation, and shock absorbency. Foamed plastic parts are now a ubiquitous part of everyday life—from food packaging to seat cushions. As the application of foamed polymers expands and diversifies, a variety of foaming techniques and equipment are available to produce very diverse range of products. Foaming methods are generally established, but very little is known about the composition of materials to be processed and the additives to enhance foam products or make the foam production more economical. The book introduces useful analytical techniques for foaming, and thoroughly discusses the environmental impact of foaming processes. Introduces the fundamental mechanisms of action of blowing agents and foaming Includes best practice guidance to help engineers and technicians improve the efficiency of their existing foaming processes Enables practitioners to select blowing agents and foaming methods more effectively, reducing the risk of poor specification Introduces useful analytical techniques for foaming Discusses the environmental impact of foaming processes

This important new handbook draws on the experience of leading industrial and academic specialists to describe virtually every type of polymer foam. The book is the intended to help scientists, engineers and technicians in their efforts to develop practical solutions for industrial design and process manufacturing challenges. It fully describes all classes of polymeric foam including their chemistry, synthesis, commercial production methods, properties and applications. Fundamentals of foam formation are also carefully explained. The internationally known contributors present data and techniques relevant to the study of polymer composites and other materials, along with manufacturing techniques for foamed and porous plastics. Amply illustrated, carefully indexed, and organized by incremental headings for easy reference, the handbook is the first comprehensive reference on the subject, offering a huge store of information in one convenient resource.

This handbook explores the applications of polymer foams, and the properties that make them suitable for so many applications, in the detail required by postgraduate students, researchers and the many industrial engineers and designers who work with polymer foam in industry. It covers the mechanical properties of foams and foam microstructure, processing of foams, mechanical testing and analysis (using Finite element analysis). In addition, it uniquely offers a broader perspective on the actual engineering of foams and foam based (or foam including) products by including nine detailed case studies which firmly plant the theory of the book in a real world context, making it ideal for both polymer engineers and chemists and mechanical engineers and product designers. * Complete coverage of the mechanical and design aspects of polymer foams from an acknowledged international expert: no other book is available with this breadth making this a plastics engineer's first choice for a single volume Handbook * Polymer foams are ubiquitous in modern life, used everywhere from running shoes to furniture, and this book includes nine extensive case studies covering each key class of application, including biomechanics * Offers a rigorous mechanical and microstructure perspective, plus a computer based chapter: Essential for engineers and designers alike.

Polymers have undoubtedly changed the world through many products that improve our lives. However, additives used to modify the overall characteristics of these materials may not be fully disclosed or understood. These additives may present possible environmental and health hazards. It is important to monitor consumer products for these compounds using high-quality reference materials and dependable analytical techniques. The Handbook for the Chemical Analysis of Plastic and Polymer Additives, Second Edition provides the necessary tools for chemists to obtain a more complete listing of additives present in a particular polymeric matrix. It is designed to serve as a valuable source for those monitoring a polymer/plastic material for regulatory or internal compliance. It also helps analysts to correctly identify the complex nature of the materials that have been added to the polymer/plastic. With 50 additional compounds, this second edition nearly doubles the number of additives in several categories, including processing aids, antistatic compounds, mould release products, and blowing agents. It includes a listing that can be cross-referenced by trade name, chemical name, CAS number, and even key mass unit ions from the GC/MS run. Addressing additives from an analytical viewpoint, this comprehensive handbook helps readers identify the additives in plastics. This information can be used to assess compliance with regulations issued by the FDA, US EPA, EU, and other agencies.

A practical handbook rather than merely a chemistry reference, Szycher's Handbook of Polyurethanes, Second Edition offers an easy-to-follow compilation of crucial new information on polyurethane technology, which is irreplaceable in a wide range of applications. This new edition of a bestseller is an invaluable reference for technologists, marketers, suppliers, and academicians who require cutting-edge, commercially valuable data on the most advanced uses for polyurethane, one of the most important and complex specialty polymers. internationally recognized expert Dr. Michael Szycher updates his bestselling industry "bible" With seven entirely new chapters and five that are revised and updated, this book summarizes vital contents from U.S. patent literature—one of the most comprehensive sources of up-to-date technical information. These patents illustrate the most useful technology discovered by corporations, universities, and independent inventors. Because of the wealth of information they contain, this handbook features many full-text patents, which are carefully selected to best illustrate the complex principles involved in polyurethane chemistry and technology. Features of this landmark reference include: Hundreds of practical formulations Discussion of the polyurethane history, key terms, and commercial importance An in-depth survey of patent literature Useful stoichiometric calculations The latest "green" chemistry applications A complete assessment of medical-grade polyurethane technology Not biased toward any one supplier’s expertise, this special reference uses a simplified language and layout and provides extensive study questions after each chapter. It presents rich technical and historical descriptions of all major polyurethanes and updated sections on medical and biological applications. These features help readers better understand developmental, chemical, application, and commercial aspects of the subject.

Flame Retardant Polymeric Materials provides a comprehensive and up-to-date overview of the field, from basic properties and mechanisms of action for flame retardants to emerging methods, materials, and industrial applications. With over 120 black and white images, Hu and Wang cover the latest in the development of novel polymer nanocomposites such as graphene, CNTs, LDHs, POSS, and techniques such as layer-by-layer assembly. These expert authors also include discussions on the important flame-retardant systems based on phosphorus, silicon, and boron. In doing so, they highlight the use of flame-retardants in varying industries, for example, construction, textiles, and aviation. This comprehensive handbook is an essential read for students and academics of physics with a particular interest in flame-retardant materials. It would also be recommended for professionals within the materials science and engineering fields.

This book extensively reviews Polypropylene (PP), the second most widely produced thermoplastic material, having been produced for over 60 years. Its synthesis, processing and application are still accompanied by vigorous R&D developments because the properties of PP are at the borderline between those of commodity and engineering thermoplastics. Readers are introduced to various tacticities and polymorphs of PP, and their effects on structural properties. Further, the book addresses the control of optical properties using nucleants, provides strategies for overcoming the limited cold/impact resistance of PP, examines in detail the effects of recycling, and presents guidelines for the property modification of PPs through foaming, filling and reinforcing with respect to target applications. Special attention is paid to descriptions and models of properties as a function of morphological variables. Last but not least, the book suggests potential practical applications of PP-based systems, especially in the packaging, appliances, building/construction, textile and automotive sectors. Each chapter, written by internationally respected scientists, reflects the current state-of-art in the respective field and offers a vital source of information for students, researchers and engineers interested in the morphology, properties, testing and modeling of PP and PP-based systems. The content is indispensable to the appropriate application of PPs and related composites.

Advances in nanotechnology have boosted the development of more efficient materials, with emerging sectors (electronics, energy, aerospace, etc.) demanding novel materials to fulfill the complex technical requirements of their products. This is the case of polymeric foams, which may display good structural properties alongside functional characteristics through a complex composition and (micro)structure in which a gas phase is combined with rigid ones, mainly based on nanoparticles, dispersed throughout the polymer matrix. In recent years, there has been an important impulse in the development of nanocomposite foams, extending the concept of nanocomposites to the field of cellular materials. This, alongside developments in new advanced foaming technologies which have allowed the generation of foams with micro, sub-micro, and even nanocellular structures, has extended the applications of more traditional foams in terms of weight reduction, damping, and thermal and/or acoustic insulation to novel possibilities, such as electromagnetic interference (EMI) shielding. This Special Issue, which consists of a total of 22 articles, including one review article written by research groups of experts in the field, considers recent research on novel polymer-based foams in all their aspects: design, composition, processing and fabrication, microstructure, characterization and analysis, applications and service behavior, recycling and reuse, etc.

This handbook will provide the reader with a profound introduction to the key subjects comprising the relatively new topic of Soft Condensed Matter. It will provide students and researchers with an authoritative overview of the field, identify key principles at play, and the most prominent ways of further development.

Because the field of plastics is one of the fastest changing areas today, the need arises to offer relevant, comprehensive material on polymers. An established source of information on modern plastics, the Plastics Technology Handbook continues to provide up-to-date coverage on the properties, processing methods, and applications of polymers. Retaining the easy-to-follow structure of the previous editions, this fourth edition includes new topics of interest that reflect recent developments and lead to better insights into the molecular behavior of polymers. New to the Fourth Edition Advances in supramolecular polymerization, flame retardancy, polymer-based nanomedicines, and drug delivery The new concept of oxo-biodegradable polymers Broadened discussion on plastic foams and foam extrusion processes More information on the processing and applications of industrial polymers, including the emerging field of nanoblends Developments in polymer synthesis and applications, such as polymeric sensors, hydrogels and smart polymers, hyperbranched polymers, shape memory polymers, polymeric optical fibers, scavenger resins, polymer nanocomposites, polymerization-filled composites, and wood-polymer composites A state-of-the-art account of the various available methods for plastics recycling Advances in the use of polymers in packaging, construction, the automotive and aerospace industries, agriculture, electronics and electrical technology, biomedical applications, corrosion prevention, and sports and marine applications Plastics Technology Handbook, Fourth Edition thoroughly covers traditional industrial polymers and their processing methods as well as contemporary polymeric materials, recent trends, and the latest applications.

Concise Polymeric Materials Encyclopedia culls the most used, widely applicable articles from the Polymeric Materials Encyclopedia - more than 1,100 - and presents them to you in a condensed, well-ordered format. Featuring contributions from more than 1,800 scientists from all over the world, the book discusses a vast array of subjects related to the: synthesis, properties, and applications of polymeric materials development of modern catalysts in preparing new or modified polymers modification of existing polymers by chemical and physical processes biologically oriented polymers This comprehensive, easy-to-use resource on modern polymeric materials serves as an invaluable addition to reference collections in the polymer field.

A comprehensive overview of biodegradable polymers, covering everything from synthesis, characterization, and degradation mechanisms while also introducing useful applications, such as drug delivery systems and biomaterial-based regenerative therapies. An introductory section deals with such fundamentals as basic chemical reactions during degradation, the complexity of biological environments and experimental methods for monitoring degradation processes. The result is a reliable reference source for those wanting to learn more about this important class of polymer materials, as well as scientists in the field seeking a deeper insight.

Polymeric foams are sturdy yet lightweight materials with applications across a variety of industries, from packaging to aerospace. As demand for these materials increase, so does innovation in the development of new processes and products. This book captures the most dynamic advances in processes, technologies, and products related to the polymeric foam market. It describes the latest business trends including new microcellular commercialization, sustainable foam products, and nanofoams. It also discusses novel processes, new and environmentally friendly blowing agents, and the development and usage of various types of foams, including bead and polycarbonate, polypropylene, polyetherimide microcellular, and nanocellular. The book also covers flame-retardant foams, rigid foam composites, and foam sandwich composites and details applications in structural engineering, electronics, and insulation. Authored by leading experts in the field, this book minimizes the gap between research and application in this important and growing area.

Handbook of Nucleating Agents gives engineers and materials scientists the information they need to increase the production rate, modify structure and morphology, and reduce haze of polymeric products with proper selection of nucleating agents and clarifying agents. Chemical origin and related properties of nucleating agents are analyzed in general terms to highlight the differences in their properties, including the essential theoretical knowledge required for correct selection and use of nucleating and clarifying agents. This includes methods of chemical modification of nucleating agents and their deposition on suitable substrates; methods and results of dispersion of nucleating agents; influence of their concentration and cooling rate on final result and rate of crystallization; nucleation efficiency of different products and the reasons behind it; and generally accepted mechanisms of nucleation. The book also covers application aspects in different formulations. Patent literature and research papers are extensively reviewed for different applications, and polymer processing methods which require use of nucleating agents are discussed, with an emphasis on the intricacies of use of nucleating agents in different polymers and products. Enables engineers to use nucleating agents more effectively to increase production rate, modify structure and morphology, and reduce haze of polymer products Provides a thorough theoretical grounding required for proper selection and use of nucleating and clarifying agents Offers an extensive review of current applications of nucleating agents in different formulations Includes analysis of the chemical origin and related properties of nucleating agents to highlight differences in their properties