Corrosion Protection At The Nanoscale

Corrosion Protection at the Nanoscale explores fundamental concepts on how metals can be protected at the nanoscale by using both nanomaterials-based solutions, including nanoalloys, noninhibitors and nanocoatings. It is an important reference resource for both materials scientists and engineers wanting to find ways to create an efficient corrosion prevention strategy. Nanostructure materials have been widely used in many products, such as print electronics, contact, interconnection, implant, nanosensors and display units to lessen the impact of corrosion. Traditional methods for protection of metals include various techniques, such as coatings, inhibitors, electrochemical methods (anodic and cathodic protections), metallurgical design are covered in this book. Nanomaterials-based protective methods can offer many advantages over their traditional counterparts, such as protection for early-stage, higher corrosion resistance, better corrosion control. This book also outlines these advantages and discusses the challenges of implementing nanomaterials as corrosion protection agents on a wide scale.

Corrosion is an expensive and potentially dangerous problem in many industries. The potential application of different nanostructured materials in corrosion protection, prevention and control is a subject of increasing interest. Corrosion protection and control using nanomaterials explores the potential use of nanotechnology in corrosion control. The book is divided into two parts. Part one looks at the fundamentals of corrosion behaviour and the manufacture of nanocrystalline materials. Chapters discuss the impact of nanotechnology in reducing corrosion cost, and investigate the influence of various factors including thermodynamics, kinetics and grain size on the corrosion behaviour of nanocrystalline materials. There are also chapters on electrodeposition and the corrosion behaviour of electrodeposited nanocrystalline materials. Part two provides a series of case studies of applications of nanomaterials in corrosion control. Chapters review oxidation protection using nanocrystalline structures at various temperatures, sol- gel and self-healing nanocoatings and the use of nanoreservoirs and polymer nanocomposites in corrosion control. With its distinguished editors and international team of expert contributors, Corrosion protection and control using nanomaterials is an invaluable reference tool for researchers and engineers working with nanomaterials in a variety of industries including, aerospace, automotive and chemical engineering as well as academics studying the unique protection and control offered by nanomaterials against corrosion. Explores the potential use of nanotechnology and nanomaterials for corrosion prevention, protection and control Discusses the impact of nanotechnology in reducing corrosion cost and investigates various factors on the corrosion behaviour of nanocrystalline materials Provides a series of case studies and applications of nanomaterials for corrosion control

This book focuses on the electrochemical and nanostructural properties of new photoanode/electrolyte combinations used in the development of novel surface-modified nanomaterials for environmental applications. As water treatment is rapidly becoming a global challenge due to the increasing complexity and number of the various pollutants present, the book explores fundamental issues relating to environmental applications of nanomaterials. It addresses relevant topics ranging from electrochemical synthesis and characterization, to applications of photoanodes in corrosion prevention and biosensors for wastewater treatment. Featuring up-to-date experimental results on nanomaterials for detection of pharmaceuticals and heavy metals in wastewater, this contributed volume is useful to electrochemical researchers, materials scientists, and chemical and civil engineers interested in advanced photoelectrochemical research for environmental applications.

Corrosion Science and Engineering is now an integral part of research throughout the world. Researchers are actively looking for an alternative eco-friendly way of developing non-toxic corrosion inhibitors from natural sources. This book discusses all the recent advancements in the corrosion field with an emphasis on natural sources which is the demand of the era to replace the commercially available toxic corrosion inhibitors.

The term ‘nanobattery’ can refer not only to the nanosized battery, but also to the uses of nanotechnology in a macro-sized battery for enhancing its performance and lifetime. Nanobatteries can offer many advantages over the traditional battery, including higher power density, shorter charging time, and longer shelf life. Nano-generators refer to the uses of nanosized devices and materials to convert mechanical, thermal and light-based energies into electricity. Similar to with traditional battery, in nanobatteries, the chemical energy is converted into electricity. This book addresses the fundamental design concepts and promising applications of nanobatteries and nanogenerators. Particular application areas include healthcare, biomedical, smart nanodevices and nanosensors, which may require new electric power sources, including self-powered ability and nanostructured electric power sources. In this regard, nanobatteries and nanogenerators represent the next generation of electric power. This is an important reference source for materials scientists, engineers and energy scientists, who are looking to increase their understanding of how nanotechnology is being used to create new energy storage and generation solutions. Outlines the major design and fabrication principles and techniques for creating nano-sized batteries and generators Demonstrates how nanotechnology is being used to make batteries and generators more powerful and longer lasting Assesses the challenges of mass manufacturing nanobatteries and nanogenerators

Nanomaterials are significant because of their unique properties that may lead to new and stimulating applications. Nanocoatings are one of the leading topics within the range of nanotechnology. Through nanoscale engineering of surfaces and layers, an enormous range of functionalities and new physical effects can be achieved. Current scenario of application of nanotechnology in the field of corrosion prevention of metals is reviewed in this compendium. Nanostructured materials (1-100 nm) are known for their outstanding mechanical and physical properties due to their extremely fine grain size and high grain boundary volume fraction. Significant progress has been made in various aspects of synthesis of nanoscale materials. The focus is now shifting from synthesis to manufacture of useful structures and coatings having greater wear and corrosion resistance.Corrosion Protection and Control Using Nanomaterials covers the latent use of nanotechnology and nanomaterials for corrosion prevention, protection and control. Recent research and developments in this area are discussed in designing efficient coating materials and alloys, which provide superior resistance to corrosion. It provides a review of the latest research findings and key applications in the field of nanomaterials. It will highlight the continued growth and new challenges in nanomaterials science, engineering, and nanotechnology, both for application development and for basic research. Furthermore, it presents on Synthesis and characterization of thermally evaporated copper bismuth sulfide thin films and development of novel corrosion techniques for a green environment. Chapters review moisture-absorbing and abrasion-resistant transparent coating on polystyrene and enhanced corrosion resistance of PVD-CrN Coatings by ALD Sealing Layers.We hope this book will be of immense interest for students, researchers and engineers working with nanomaterials in an assortment of industries with, aerospace, automotive and chemical engineering as well as academics studying the distinctive protection and control presented by nanomaterials against corrosion.

Biodegradation and Biodeterioration at the Nanoscale describes the biodegradation and biodeterioration of materials in the presence of nanomaterials. The book's chapters focus on the basic principles, action mechanisms and promising applications of advanced nanomaterials, along with their integration with biotechnological processes for controlled degradation and deterioration of materials. In addition, the current research indications, positive or negative environmental impacts, legislation and future directions are also discussed. This book is an important reference source for researchers, engineers and scientists working in environmental remediation, biotechnology, materials science, corrosion and nanotechnology. Provides detailed coverage on how nano-biomaterials degrade and deteriorate Compares how different types of bionanomaterials decompose Explains how the priorities of bionanomaterials affect their deterioration rate

Inorganic Anticorrosive Materials (IAMs): Past, Present, and Future Perspectives covers the anticorrosive effects of?inorganic materials and metal?oxides in particular. The book?presents?the?latest?developments?in corrosion inhibition and?discusses?future opportunities.?It?also addresses?the fundamental characteristics, synthesis, inhibition mechanisms,?and applications of?metal oxides as?corrosion inhibitors in industry?and provides a chronological overview of the growth of the field.?The book concludes with discussions about commercialization and economics. This book is an indispensable reference for scholars, chemical engineers, chemists, and materials scientists working in research and development and in academia who require comprehensive knowledge of corrosion-inhibition mechanisms. Utilizes metal oxides as corrosion inhibitors for usage in modern industrial platforms Evaluates corrosion inhibitors as prime options for sustainable and transformational opportunities Provides up-to-date reference materials, including websites of interest and information about ongoing research

Coatings act as multifunctional and smart materials for products, as well as serving as physical barriers or decoration. Nanomaterials-enforced coatings are smarter, stronger and more durable. The barrier performance of organic coatings is enhanced by the incorporation of nanofillers, by decreasing the porosity and zigzagging the diffusion path for deleterious species. Coatings containing nanofillers, therefore have significant barrier properties for corrosion protection and reducing the trend for the coating to blister or delaminate. In addition, the functionalization of nanomaterials has led to advances in smart nanocomposite coatings, such as self-healing, anti-fouling, self-cleaning, antibacterial and cooling coatings. Nanomaterials-based Coatings emphasizes the fundamental concepts and promising applications of nanomaterial-based coatings in anticorrosion, antiwear, antibacterial, antifugal, self-leaning, superhydrophobic, superhard, super heat resistance, solar reflective, photocatalytic and radar absorbing coatings. It is an important information source for those seeking to understand the underlying phenomenal and fundamental mechanisms through which nanoparticles interact with polymeric and metallic matrices to create stronger coatings, and what their major applications are. Highlights the latest methods in design, preparation and characterization techniques for nanomaterials-based coatings Discusses emerging applications of nanomaterials-based coatings, including substrates protection, sustainable energy, environment and healthcare Assesses the major challenges in making nanomaterials-based coatings more reliable and cost-effective

For centuries, electrochemistry has played a key role in technologically important areas such as electroplating or corrosion. In recent decades, electrochemical methods are receiving increasing attention in important strongly growing fields of science and technology such as nanosciences (nanoelectrochemistry) and life-sciences (organic and biological electrochemistry). Characterization, modification and understanding of various electrochemical interfaces or electrochemical processes at the nanoscale, has led to a huge increase of the scientific interest in electrochemical mechanisms as well as of application of electrochemical methods in novel technologies. This book presents exciting emerging scientific and technological aspects of the introduction of the nanodimension in electrochemical approaches are presented in 12 chapters/subchapters.

Supramolecular chemistry, "the chemistry beyond the molecule", is a fascinating realm of modern science. The design of novel supramolecular structures, surfaces, and techniques are at the forefront of research in different application areas, including corrosion and biofouling protection. A team of international experts provide a comprehensive view of the applications and potential of supramolecular chemistry in corrosion and biofouling prevention. Chapter topics include types and fundamentals of supramolecules, supramolecular polymers and gels, host-guest inclusion compounds, organic-inorganic hybrid materials, metallo-assemblies, cyclodextrins, crown ethers, mesoporous silica and supramolecular structures of graphene and other advances. Additional Features include: Focuses on different aspects of supramolecular chemistry in corrosion and biofouling prevention. Comprehensively covers supramolecular interactions that can provide better corrosion and biofouling protection. Provides the latest developments in self-healing coatings. Explores recent research advancements in the suggested area. Includes case studies specific to industries. The different supramolecular approaches being investigated to control corrosion and biofouling are gathered in one well-organized reference to serve senior undergraduate and graduate students, research students, engineers, and researchers in the fields of corrosion science & engineering, biofouling, and protective coatings.

The goal of this project was to explore and develop a novel class of nanoscale reinforced ceramic coatings for high temperature (600-1000 C) corrosion protection of metallic components in a coal-fired environment. It was focused on developing coatings that are easy to process and low cost. The approach was to use high-yield preceramic polymers loaded with nano-size fillers. The complex interplay of the particles in the polymer, their role in controlling shrinkage and phase evolution during thermal treatment, resulting densification and microstructural evolution, mechanical properties and effectiveness as corrosion protection coatings were investigated. Fe-and Ni-based alloys currently used in coal-fired environments do not possess the requisite corrosion and oxidation resistance for next generation of advanced power systems. One example of this is the power plants that use ultra supercritical steam as the working fluid. The increase in thermal efficiency of the plant and decrease in pollutant emissions are only possible by changing the properties of steam from supercritical to ultra supercritical. However, the conditions, 650 C and 34.5 MPa, are too severe and result in higher rate of corrosion due to higher metal temperatures. Coating the metallic components with ceramics that are resistant to corrosion, oxidation and erosion, is an economical and immediate solution to this problem. Good high temperature corrosion protection ceramic coatings for metallic structures must have a set of properties that are difficult to achieve using established processing techniques. The required properties include ease of coating complex shapes, low processing temperatures, thermal expansion match with metallic structures and good mechanical and chemical properties. Nanoscale reinforced composite coatings in which the matrix is derived from preceramic polymers have the potential to meet these requirements. The research was focused on developing suitable material systems and processing techniques for these coatings. In addition, we investigated the effect of microstructure on the mechanical properties and oxidation protection ability of the coatings. Coatings were developed to provide oxidation protection to both ferritic and austentic alloys and Ni-based alloys. The coatings that we developed are based on low viscosity pre-ceramic polymers. Thus they can be easily applied to any shape by using a variety of techniques including dip-coating, spray-coating and painting. The polymers are loaded with a variety of nanoparticles. The nanoparticles have two primary roles: control of the final composition and phases (and hence the properties); and control of the shrinkage during thermal decomposition of the polymer. Thus the selection of the nanoparticles was the most critical aspect of this project. Based on the results of the processing studies, the performance of selected coatings in oxidizing conditions (both static and cyclic) was investigated.

Called "a useful contribution to the current litereture on corrosion science, engineering, and technology" by Corrosion Review, this book offers real-world applications and problem-solving techniques to reduce the occurrence of pits, cracks, and deterioration in industrial, automotive, marine, and electronic structures. It details the electrochemic

A smart coating is defined as one that changes its properties in response to an environmental stimulus. The Handbook of Smart Coatings for Materials Protection reviews the new generation of smart coatings for corrosion and other types of material protection. Part one explores the fundamentals of smart coatings for materials protection including types, materials, design, and processing. Chapters review corrosion processes and strategies for prevention; smart coatings for corrosion protection; techniques for synthesizing and applying smart coatings; multi-functional, self-healing coatings; and current and future trends of protective coatings for automotive, aerospace, and military applications. Chapters in part two focus on smart coatings with self-healing properties for corrosion protection, including self-healing anticorrosion coatings for structural and petrochemical engineering applications; smart self-healing coatings for corrosion protection of aluminum alloys, magnesium alloys and steel; smart nanocoatings for corrosion detection and control; and recent advances in polyaniline-based organic coatings for corrosion protection. Chapters in part three move on to highlight other types of smart coatings, including smart self-cleaning coatings for corrosion protection; smart polymer nanocomposite water- and oil-repellent coatings for aluminum; UV-curable organic polymer coatings for corrosion protection of steel; smart epoxy coatings for early detection of corrosion in steel and aluminum; and structural ceramics with self-healing properties. The Handbook of Smart Coatings for Materials Protection is a valuable reference for those concerned with preventing corrosion, particularly of metals, professionals working within the surface coating industries, as well as all those with an academic research interest in the field. Reviews the new generation of smart coatings for corrosion and other types of material protection Explores the fundamentals of smart coatings for materials protection including types, materials, design, and processing Includes a focus on smart coatings with self-healing properties for corrosion protection

With contributions from experts from both academia and industry, this book provides up-to-date reviews and promising approaches for corrosion control of metals and alloys via sustainable biopolymers and carbon nanomaterials coatings, focusing on the wonder material “graphene” which is more solid than steel. This book delivers essential information for improving the environmental and economic viability of current coating technologies. It is also a valuable reference for those who are interested in corrosion science and corrosion protection including professionals from the industry as well as academia.

This book contains thirty articles on various topics related to the corrosion and protection of metallic materials. This topic is of strong actuality both due to the aging of plants and infrastructures that require checks and maintenance, and to the use of traditional materials in increasingly aggressive environments, added to the need of changing the current anti-corrosion systems with less environmental impact methods. Finally, the new development of innovative materials, such as additive manufacturing or high-entropy alloys, needs the characterization of their corrosion behavior. In this issue, there are works on new alloys obtained for additive manufacturing or high entropy, on the study of corrosion and stress corrosion cracking and hydrogen embrittlement mechanisms, through electrochemical and microscopical techniques, studies on low environmental impact inhibitors and biocides, as well as ceramic and metal protective coatings. Finally, there are works on the study of the residual mechanical resistance of corroded infrastructures and on monitoring and non-destructive control. In this way, the book therefore offers a somewhat varied panorama of research trends in the field.

In this new handbook, top researchers from around the world discuss recent academic and industrial advances in designing ceramic coatings and materials. They describe the role of nanotechnology in designing high performance nanoceramic coatings and materials in terms of the unique advantages that can be gained from the nano scale, including the latest techniques for the synthesis and processing of ceramic and composite coatings for different applications. Focuses on the most advanced technologies for industry-oriented nano-ceramic and nano-composite coatings, including recent challenges for scaling up nano-based coatings in industry Covers the latest evaluation methods for measuring coatings performance Discusses novel approaches for improving the performance of ceramic and composite coatings and materials via nanotechnology Provides the most recent and advanced techniques for surface characterization

Advances In Smart Coatings And Thin Films For Future Industrial and Biomedical Engineering Applications discusses in detail, the recent trends in designing, fabricating and manufacturing of smart coatings and thin films for future high-tech. industrial applications related to transportation, aerospace and biomedical engineering. Chapters cover fundamental aspects and diverse approaches used to fabricate smart self-healing anti-corrosion coatings, shape-memory coatings, polymeric and nano-bio-ceramic cotings, bio-inspired and stimuli-responsive coatings for smart surfaces with antibacterial activkity and controlled wettability, and electrically conductive coatings and their emerging applications. With the emphasis on advanced methodologies and recent emerging applications of smart multifunctional coatings and thin films, this book is essential reading for materials scientists and rsearchers working in chemical sciences, advanced materials, sensors, pharmaceutical and biomedical engineering. Discusses the most recent advances and innovations in smart multifunctional coatings and thin films in the transportation, aerospace and biomedical engineering industries Highlights the synthesis methods, processing, testing and characterization of smart coatings and thin films Reviews the current prospects and future trends within the industry

A Comprehensive Review of Developing Environmentally Friendly Lubricants A push from environmentally savvy consumers along with recent changes in governmental regulations have paved the way for a marketplace of products with high levels of environmental performance. Fueled by the growing demand for biobased lubricants, Environmentally Friendly and Biobased Lubricants highlights the development of environmentally friendly additives that are compatible with environmental regulations and describes the approaches being used in this emerging area. Derived from research topics shared over the years at various technical sessions of the Society of Tribologists and Lubrication Engineers (STLE) Annual Meetings, the book includes a critical assessment of gaps and weaknesses in the field of environmentally friendly fluids and biobased lubricants. Each chapter is written by authors selected from the environmentally friendly fluids and biobased lubricants sessions of STLE and also incorporates input from prominent researchers invited to take part in the book. Expert contributors discuss the control, production, usage, and disposal of lubricants; factor in related policies, laws, and regulations around the world; and include case studies demonstrating the uses and values of commercially viable biobased lubricants. The book is divided into five sections that cover advanced environmentally friendly base oils and feedstocks, biobased hydraulic lubricants and biodegradability, chemically/enzymatically modified environmentally friendly base oils, vegetable oil–based environmentally friendly fluids, and additives for environmentally friendly fluids.