Hydrogen Safety for Energy Applications

Hydrogen Safety highlights physiological, physical, and chemical hazards associated with hydrogen production, storage, distribution, and use systems. It also examines potential accident scenarios that could occur with hydrogen use under certain conditions. The number of potential applications for hydrogen continues to grow—from cooling power station generators to widespread commercial use in hydrogen fuel-cell vehicles and other fuel-cell applications. However, this volatile substance poses unique challenges, including easy leakage, low ignition energy, a wide range of combustible fuel-air mixtures, buoyancy, and its ability to embrittle metals that are required to ensure safe operation. Focused on providing a balanced view of hydrogen safety—one that integrates principles from physical sciences, engineering, management, and social sciences—this book is organized to address questions associated with the hazards of hydrogen and the ensuing risk associated with its industrial and public use. What are the properties of hydrogen that can render it a hazardous substance? How have these hazards historically resulted in undesired incidents? How might these hazards arise in the storage of hydrogen and with its use in vehicular transportation? The authors address issues of inherently safer design, safety management systems, and safety culture. They highlight hydrogen storage facilities —which pose greater hazards because of the increased quantities stored and handled—and the dangers of using hydrogen as a fuel for transport. Presented experiments are included to verify computer simulations with the aid of computational fluid dynamics (CFD) of both gaseous and liquefied hydrogen. The book also provides an overview of the European Commission (EC) Network of Excellence for Hydrogen Safety (HySafe) and presents various case studies associated with hydrogen and constructional materials. It concludes with a brief look at future research requirements and current legal requirements for hydrogen safety.

The overall goal of the HySEA project is to conduct pre-normative research on vented hydrogen deflagrations with an aim to provide recommendations for European and international standards on hydrogen explosion venting mitigation systems, and to develop and validate engineering models (EMs), computational fluid dynamics (CFD) and finite element (FE) methods that can be verified and validated against data from experiments performed in containers and smaller enclosures with industry-representative obstacles.

Hydrogen Safety for Energy Applications: Engineering Design, Risk Assessment, and Codes and Standards presents different aspects of the contemporary knowledge regarding hazard, risk and safety connected with hydrogen systems. In the initial part of the book, the hydrogen fundamentals and the main hydrogen technologies are described and discussed. It then explores scientific aspects of the possible sources and consequences of accidental events that can occur when hydrogen is used, including in its vehicular applications. Risk assessment, as well as the safety measures/safety barriers applicable in such situations, are considered. A short survey concerning legal aspects is presented in the last part. Provides factual material, such as models, correlations, tables, nomograms and formulas, that can be used to perform evaluations and propose mitigation measures to diminish risk probability in hydrogen energy systems Presents reference data and detailed descriptions and guidelines of the contemporary risk assessment methodologies Covers accident phenomena and consequences of accidents specific to hydrogen systems in a widely applicable way for the wide variety of hydrogen activities

Hydrogen Infrastructure for Energy Applications: Production, Storage, Distribution and Safety examines methodologies, new models and innovative strategies for the optimization and optimal control of the hydrogen logistic chain, with particular focus on a network of integrated facilities, sources of production, storage systems, infrastructures and the delivery process to the end users through hydrogen refueling stations. The book discusses the main motivations and criteria behind the adoption of hydrogen as an energy carrier or future fuel alternative. It presents current research in hydrogen production processes, especially from renewable energy sources, as well as storage and distribution. The book also reviews methods to model hydrogen demand uncertainties and challenges for the design of the future hydrogen supply chain. The authors go on to explore the network planning of hydrogen infrastructures, the safety and risk issues in hydrogen logistics and their future expectations. Energy engineering professionals, researchers and graduate students will find this a helpful resource to understand the methodologies used to assess the feasibility for developing hydrogen supply chains, hydrogen infrastructure and safety practices. Energy analysts and government agents can benefit from the book's detailed discussion of hydrogen energy applicability. Describes in detail the current state of the available approaches for the planning and modeling of the hydrogen infrastructure Discusses safety issues related to hydrogen in different components of its logistic chain and the methodological approach to evaluate risks that results from hydrogen accidents, including a mathematical model to assess the hazard and consequences of an accident scenario of hydrogen in pipelines Proposes a decision support system for hydrogen energy exploitation, focusing on some specific planning aspects, such as selection of locations with high hydrogen production, based mainly on the use of solar and wind energies Presents a short-term scenario of hydrogen distribution for automotive use, with a concrete, detailed, operative plan for a network of refueling service stations for the hydrogen economy

Compendium of Hydrogen Energy, Volume 2: Hydrogen Storage, Distribution and Infrastructure focuses on the storage and transmission of hydrogen. As many experts believe the hydrogen economy will, at some point, replace the fossil fuel economy as the primary source of the world’s energy, this book details hydrogen storage in pure form, including chapters on hydrogen liquefaction, slush production, as well as underground and pipeline storage. Other sections in the book explore physical and chemical storage, including environmentally sustainable methods of hydrogen production from water, with final chapters dedicated to hydrogen distribution and infrastructure. Covers a wide array of methods for storing hydrogen, detailing hydrogen transport and the infrastructure required for transition to the hydrogen economy Written by leading academics in the fields of sustainable energy and experts from the world of industry Part of a very comprehensive compendium which looks at the entirety of the hydrogen energy economy

Science and Engineering of Hydrogen-Based Energy Technologies explores the generation of energy using hydrogen and hydrogen-rich fuels in fuel cells from the perspective of its integration into renewable energy systems using the most sound and current scientific knowledge. The book first examines the evolution of energy utilization and the role expected to be played by hydrogen energy technologies in the world’s energy mix, not just for energy generation, but also for carbon capture, storage and utilization. It provides a general overview of the most common and promising types of fuel cells, such as PEMFCs, SOFCs and direct alcohol fuel cells. The co-production of chemical and electrolysis cells, as well as the available and future materials for fuel cells production are discussed. It then delves into the production of hydrogen from biomass, including waste materials, and from excess electricity produced by other renewable energy sources, such as solar, wind, hydro and geothermal. The main technological approaches to hydrogen storage are presented, along with several possible hydrogen energy engineering applications. Science and Engineering of Hydrogen-Based Energy Technologies’s unique approach to hydrogen energy systems makes it useful for energy engineering researchers, professionals and graduate students in this field. Policy makers, energy planning and management professionals, and energy analysts can also benefit from the comprehensive overview that it provides. Presents engineering fundamentals, commercially deployed technologies, up-and-coming developments and applications through a systemic approach Explores the integration of hydrogen technologies in renewable energy systems, including solar, wind, bioenergy and ocean energy Covers engineering standards, guidelines and regulations, as well as policy and social aspects for large-scale deployment of these technologies

Hydrogen, as an energy carrier, is widely regarded as a potential cost effective, renewable, and clean energy alternative to petroleum in order to mitigate energy shortage and global climate warming issues that the world is currently facing. However, storage of hydrogen is a substantial challenge, especially for applications in vehicles with fuel cells that use proton-exchange membranes (PEMs). Therefore, scientific community has started focusing their research activities on developing advanced hydrogen storage materials through nanotechnology. The book presents a wide variety of nanostructured materials used for application in hydrogen storage, covering chemical and physical storage approaches. The research topics include computational design, synthesis, processing, fabrication, characterization, properties and applications of nanomaterials in hydrogen storage systems.

The fields covered by the hydrogen energy topic have grown rapidly, and now it has become clearly multidisciplinary. In addition to production, hydrogen purification and especially storage are key challenges that could limit the use of hydrogen fuel. In this book, the purification of hydrogen with membrane technology and its storage in "solid" form using new hydrides and carbon materials are addressed. Other novelties of this volume include the power conditioning of water electrolyzers, the integration in the electric grid of renewable hydrogen systems and the future role of microreactors and micro-process engineering in hydrogen technology as well as the potential of computational fluid dynamics to hydrogen equipment design and the assessment of safety issues. Finally, and being aware that transportation will likely constitute the first commercial application of hydrogen fuel, two chapters are devoted to the recent advances in hydrogen fuel cells and hydrogen-fueled internal combustion engines for transport vehicles. Hydrogen from water and biomass considered Holistic approach to the topic of renewable hydrogen production Power conditioning of water electrolyzers and integration of renewable hydrogen energy systems considered Subjects not included in previous books on hydrogen energy Micro process technology considered Subject not included in previous books on hydrogen energy Applications of CFD considered Subject not included in previous books on hydrogen energy Fundamental aspects will not be discussed in detail consciously as they are suitably addressed in previous books Emphasis on technological advancements Chapters written by recognized experts Up-to date approach to the subjects and relevant bibliographic references

Understand, Select, and Design Sensors for Hydrogen-Based Applications The use of hydrogen generated from renewable energy sources is expected to become an essential component of a low-carbon, environmentally friendly energy supply, spurring the worldwide development of hydrogen technologies. Sensors for Safety and Process Control in Hydrogen Technologies provides practical, expert-driven information on modern sensors for hydrogen and other gases as well as physical parameters essential for safety and process control in hydrogen technologies. It illustrates how sensing technologies can ensure the safe and efficient implementation of the emerging global hydrogen market. The book explains the various facets of sensor technologies, including practical aspects relevant in hydrogen technologies. It presents a comprehensive and up-to-date account of the theory (physical and chemical principles), design, and implementations of sensors in hydrogen technologies. The authors also offer guidance on the development of new sensors based on the analysis of the capabilities and limitations of existing sensors with respect to current performance requirements. Suitable for both technical and non-technical personnel, the book provides a balance between detailed descriptions and simple explanations. It gives invaluable insight into the role sensors play as key enabling devices for both control and safety in established and emerging hydrogen technologies.

This book introduces readers to hydrogen as an essential energy carrier for use with renewable sources of primary energy. It provides an overview of the state of the art, while also highlighting the developmental and market potential of hydrogen in the context of energy technologies; mobile, stationary and portable applications; uninterruptible power supplies and in the chemical industry. Written by experienced practitioners, the book addresses the needs of engineers, chemists and business managers, as well as graduate students and researchers.

Hydrogen and Bioenergy: Integration Pathways for Renewable Energy Applications focuses on the nexus between hydrogen and carbon compounds as energy carriers, with a particular focus on renewable energy solutions. This book explores opportunities for integrating hydrogen in the bioenergy value chain, such as adding hydrogen to upgrade biofuels and lower CO2 emissions during production. The book also takes the inverse path to examine hydrogen production by chemical and biological routes from various bioresources, including solid waste, wastewater, agricultural products and algae. This broad coverage of technologies and applications presents a unique resource for researchers and practitioners developing integrated hydrogen and bioenergy technologies. This book will also be useful for graduate students and new researchers, presenting an introductory resource in the areas of hydrogen and bioenergy. Energy planners and engineers will also benefit from this content when designing and deploying hydrogen infrastructure for power, heating and transportation. Provides a comprehensive picture of hydrogen generation from biomass, as well as other sources of hydrogen for power, heating, transportation and storage applications Explores the ways hydrogen can be utilized in combination with bio-derived hydrocarbon chains to produce a variety of substitutes for fossil fuel-based petrochemicals Fills the gap between theoretical knowledge and technology viability Analyzes how these technologies fit into an overall energy strategy targeted at expanding the renewable energy sector

As the dependence on the depleting fossils fuels continues and global warming increases, we need to find an energy system that is renewable and sustainable, efficient and cost-effective, convenient and safe. Hydrogen has been proposed as the perfect fuel to sustain the energy system. The availability of a reliable and cost-effective supply, safe and efficient storage, and convenient end use of hydrogen will be essential for a transition to a hydrogen economy. Research is being conducted throughout the world for the development of safe, cost-effective hydrogen production, storage, and end-use technologies that support and foster this transition. Hydrogen Economy discusses the strategies and roadmaps of introducing hydrogen as the alternate source of fuel for sustainable development. The book examines the link between development and energy, prospects of sustainable development, significance of hydrogen energy economy. It provides an authoritative and up-to-date scientific account of hydrogen generation, storage, transportation, and safety. Key Features: · Explains the significance of hydrogen economy · Examines the feasibility of transporting, distributing and utilizing hydrogen · Assesses the safety of using hydrogen and potential hazards Contents: Preface 1. Energy and Development · How Energy is Measured? · Fossil Fuels · Contribution of Non-fossil Energy Sources to Global Primary Energy Mix 2. Significance of Hydrogen Economy · Energy Crisis · Environmental Effects of Using Fossil Fuels · Energy and Environment · Sustainable Development · Transition to the Hydrogen Economy 3. Hydrogen Production 4. Hydrogen Storage · Fundamentals of Hydrogen · Hydrogen Embrittlement · Introduction to Packaging and Storage of Hydrogen · Standardization for Hydrogen Gas Cylinders · ASME Code Symbol Stamp · Hydrogen Liquefaction · Liquid Hydrogen Storage · Hydrogen Storage in Metal Hydrides · Developing Hydrogen Storage Media · On-board Hydrogen Storage · Choice of Storage Method 5. Transportation, Distribution, and Utilization of Hydrogen · Transportation of Hydrogen · Compressed Gas Transport · Transfer of Hydrogen Gas 6. Hydrogen Hazards Assessment and Safety · Terms and Definitions · Hazard Analysis · Choosing a Methodology · Hydrogen Hazards · Mandated Requirements · Hydrogen Safety Appendix 1: Liquid Hydrogen Handler’s Qualification Training 2: Scaling Laws, Explosions, Blast Effects, and Fragmentation 3: Hydrogen Sensing and Detection 4: Relief Devices Bibliography Index About the Authors

The demand for secure, affordable and clean energy is a priority call to humanity. Challenges associated with conventional energy resources, such as depletion of fossil fuels, high costs and associated greenhouse gas emissions, have stimulated interests in renewable energy resources. For instance, there have been clear gaps and rushed thoughts about replacing fossil-fuel driven engines with electric vehicles without long-term plans for energy security and recycling approaches. This book aims to provide a clear vision to scientists, industrialists and policy makers on renewable energy resources, predicted challenges and emerging applications. It can be used to help produce new technologies for sustainable, connected and harvested energy. A clear response to economic growth and clean environment demands is also illustrated.

Hydrogen Power: An Introduction to Hydrogen Energy and its Applications explains how hydrogen is produced, used, and handled and shows that the use of chemical hydrogen power has enormous advantages as an energy storage, transport, and use medium. Organized into seven chapters, this book first describes the chemical and physical properties of hydrogen. Subsequent chapters elucidate the current industrial uses of hydrogen, methods of producing hydrogen, and hydrogen transportation and storage. Hydrogen safety and environmental considerations are also addressed.

Compendium of Hydrogen Energy Volume 4: Hydrogen Use, Safety and the Hydrogen Economy focuses on the uses of hydrogen. As many experts believe the hydrogen economy will, at some point, replace the fossil fuel economy as the primary source of the world’s energy, this book investigates the uses of this energy, from transport, to stationary and portable applications, with final sections discussing the difficulties and possibilities of the widespread adoption of the hydrogen economy. Written by both leading academics in the fields of sustainable energy and experts from the world of industry Part of a very comprehensive compendium which across four volumes looks at the entirety of the hydrogen energy economy Covers a wide array of hydrogen uses, and details safety tactics, hydrogen applications in transport, and the hydrogen economy as a whole

The announcement of a hydrogen fuel initiative in the President’s 2003 State of the Union speech substantially increased interest in the potential for hydrogen to play a major role in the nation’s long-term energy future. Prior to that event, DOE asked the National Research Council to examine key technical issues about the hydrogen economy to assist in the development of its hydrogen R&D program. Included in the assessment were the current state of technology; future cost estimates; CO2 emissions; distribution, storage, and end use considerations; and the DOE RD&D program. The report provides an assessment of hydrogen as a fuel in the nation’s future energy economy and describes a number of important challenges that must be overcome if it is to make a major energy contribution. Topics covered include the hydrogen end-use technologies, transportation, hydrogen production technologies, and transition issues for hydrogen in vehicles.

Nanomaterials for Hydrogen Storage Applications introduces nanomaterials and nanocomposites manufacturing and design for hydrogen storage applications. The book covers the manufacturing, design, characterization techniques and hydrogen storage applications of a range of nanomaterials. It outlines fundamental characterization techniques for nanocomposites to establish their suitability for hydrogen storage applications. Offering a sound knowledge of hydrogen storage application of nanocomposites, this book is an important resource for both materials scientists and engineers who are seeking to understand how nanomaterials can be used to create more efficient energy storage solutions. Assesses the characterization, design, manufacture and application of different types of nanomaterials for hydrogen storage Outlines the major challenges of using nanomaterials in hydrogen storage Discusses how the use of nanotechnology is helping engineers create more effective hydrogen storage systems

How hydrogen -- nonpolluting and easy to produce -- could become the fuel of the future.

Portable Hydrogen Energy Systems: Fuel Cells and Storage Fundamentals and Applications covers the basics of portable fuel cells, their types, possibilities for fuel storage, in particular for hydrogen as fuel, and their potential application. The book explores electrochemistry, types, and materials and components, but also includes a chapter on the particularities of their use in portable devices, with a focus on proton exchange membrane (PEM) type. Topics cover fuel storage for these cells, in particular hydrogen storage and an analysis of current possibilities. In addition, portable fuel cell systems are examined, covering auxiliary elements required for operation and possibilities for their miniaturization. Engineers and developers of portable applications and electricity will find this book to provide fundamental information on the possibilities of portable hydrogen fuel cells, including costs and market information, for their planning, modeling, development and deployment. Graduate students and lecturers will find this to be a complementary resource in general hydrogen and fuel cell courses or in specialized courses covering portable systems. Presents a current view of the fundamentals and possibilities of portable hydrogen fuel cells, also comparing them with other market solutions, such as batteries Examines the applications where portable hydrogen fuel cell technology is a viable solution Explores future trends and needs in terms of materials, components and systems to improve the possibilities to make hydrogen fuel cells competitive and reliable for future portable applications