Direct Liquid Fuel Cells

Direct Liquid Fuel Cells is a comprehensive overview of the fundamentals and specificities of the use of methanol, ethanol, glycerol, formic acid and formate, dimethyl ether, borohydride, hydrazine and other promising liquid fuels in fuel cells. Each chapter covers a different liquid fuel-based fuel cell such as: Anode catalysts of direct methanol fuel cells (DMFCs), future system designs and future trends for direct ethanol fuel cells (DEFCs), development of catalysts for direct glycerol fuel cells (DGFCs), the mechanisms of the reactions taking place at the anode and cathode electrodes, and the reported anode catalysts for direct formic acid fuel cell (DFAFC) and direct formate fuel cell (DFFC), characteristics of direct dimethyl ether fuel cell (DDMEFC), including its electrochemical and operating systems and design, the developments in direct borohydride fuel cells, the development of catalysts for direct hydrazine fuel cells (DHFCs), and also the uncommonly used liquids that have a potential for fuel cell applications including 2-propanol, ethylene glycol, ascorbic acid and ascorbate studied in the literature as well as utilization of some blended fuels. In each part, the most recent literature is reviewed and the state of the art is presented. It also includes examples of practical problems with solutions and a summarized comparison of performance, advantages, and limitations of each type of fuel cell discussed. Direct Liquid Fuel Cells is not a typical textbook but rather designed as a reference book of which any level of students (undergraduate or graduate), instructors, field specialists, industry and general audience, who benefit from current and complete understanding of the many aspects involved in the development and operation of these types of fuel cells, could make use of any chapter when necessary. Presents information on different types of direct liquid fuel cells. Explores information under each section, for specific fuel-based fuel cells in more detail in terms of the materials used. Covers three main sections: direct alcohol, organic fuel-based and inorganic fuel-based fuel cells

Direct Liquid Fuel Cells is a comprehensive overview of the fundamentals and specificities of the use of methanol, ethanol, glycerol, formic acid and formate, dimethyl ether, borohydride, hydrazine and other promising liquid fuels in fuel cells. Each chapter covers a different liquid fuel-based fuel cell such as: Anode catalysts of direct methanol fuel cells (DMFCs), future system designs and future trends for direct ethanol fuel cells (DEFCs), development of catalysts for direct glycerol fuel cells (DGFCs), the mechanisms of the reactions taking place at the anode and cathode electrodes, and the reported anode catalysts for direct formic acid fuel cell (DFAFC) and direct formate fuel cell (DFFC), characteristics of direct dimethyl ether fuel cell (DDMEFC), including its electrochemical and operating systems and design, the developments in direct borohydride fuel cells, the development of catalysts for direct hydrazine fuel cells (DHFCs), and also the uncommonly used liquids that have a potential for fuel cell applications including 2-propanol, ethylene glycol, ascorbic acid and ascorbate studied in the literature as well as utilization of some blended fuels. In each part, the most recent literature is reviewed and the state of the art is presented. It also includes examples of practical problems with solutions and a summarized comparison of performance, advantages, and limitations of each type of fuel cell discussed. Direct Liquid Fuel Cells is not a typical textbook but rather designed as a reference book of which any level of students (undergraduate or graduate), instructors, field specialists, industry and general audience, who benefit from current and complete understanding of the many aspects involved in the development and operation of these types of fuel cells, could make use of any chapter when necessary. Presents information on different types of direct liquid fuel cells. Explores information under each section, for specific fuel-based fuel cells in more detail in terms of the materials used. Covers three main sections: direct alcohol, organic fuel-based and inorganic fuel-based fuel cells

This first book to focus on a comprehensive description on DMFC electrocatalysis draws a clear picture oft he current status of DMFC technology, especially the advances, challenges and perspectives in the field. Leading researchers from universities, government laboratories and fuel cell industries in North America, Europe and Asia share their knowledge and information on recent advances in the fundamental theories, experimental methodologies and research achievements. In order to help readers better understand the science and technology of the subject, some important and representative figures, tables, photos, and comprehensive lists of reference papers are also included, such that all the information needed on this topic may be easily located. An indispensable source for physical, catalytic, electro- and solid state chemists, as well as materials scientists and chemists in industry.

Direct Methanol Fuel Cell Technology presents the overall progress witnessed in the field of DMFC over the past decade, highlighting the components, materials, functions, properties and features, designs and configurations, operations, modelling, applications, pros and cons, social, political and market penetration, economics and future directions. The book discusses every single aspect of DMFC device technology, the associated advantages and drawbacks of state-of-the-art materials and design, market opportunities and commercialization aspects, and possible future directions of research and development. This book, containing critical analyses and opinions from experts around the world, will garner considerable interest among actual users/scientists/experts. Analyzes developments of membrane electrolytes, electrodes, catalysts, catalyst supports, bipolar plates, gas diffusion layers and flow channels as critical components of direct methanol fuel cells Includes modeling of direct methanol fuel cells to understand their scaling up potentials Discusses commercial aspects of direct methanol fuel cells in terms of market penetration, end application, cost, viability, reliability, social and commercial perception, drawbacks and prospects

Fuel Cells is a concise, up-to-date and accessible guide to the evolution of the use of electrochemistry to generate power. The author provides a comprehensive exploration of the history of fuel cells, the environmental concerns which came into prominence in the 1980s and the economic factors associated with this method of power generation. Examples discussed include Alkaline Fuel Cells, Phosphoric Acid Fuel Cells, Molton Carbonate Fuel Cells and Solid Oxide Fuel Cells, making this a valuable and insightful read for those in the power generation market and those in electrochemistry, such as engineers, managers and academics. Explores multiple variations of fuel cell technology and evaluates their cost and application Provides detailed historical context, beginning in 1839 with the development of electrolysis Discusses the most up-to-date advancements and methods of fuel cell technology today

A low contaminant formic acid fuel is especially suited toward use in a direct organic liquid fuel cell. A fuel of the invention provides high power output that is maintained for a substantial time and the fuel is substantially non-flammable. Specific contaminants and contaminant levels have been identified as being deleterious to the performance of a formic acid fuel in a fuel cell, and embodiments of the invention provide low contaminant fuels that have improved performance compared to known commercial bulk grade and commercial purified grade formic acid fuels. Preferred embodiment fuels (and fuel cells containing such fuels) including low levels of a combination of key contaminants, including acetic acid, methyl formate, and methanol.

"This book extracts the most important information on fuel cells, analyzes it, and assesses its scientific value and technical importance. It provides a full yet concise description of all the important aspects of fuel cells from major types to their historical development to inherent scientific and engineering problems and their commercialization and applications. This edition adds two new chapters, one on structural and wetting properties of porous fuel cell components and the other on fuel cells with mixed reactant supply, and updates all chapters with current knowledge for each topic"--

Fuel Cells and Hydrogen: From Fundamentals to Applied Research provides an overview of the basic principles of fuel cell and hydrogen technology, which subsequently allows the reader to delve more deeply into applied research. In addition to covering the basic principles of fuel cells and hydrogen technologies, the book examines the principles and methods to develop and test fuel cells, the evaluation of the performance and lifetime of fuel cells and the concepts of hydrogen production. Fuel Cells and Hydrogen: From Fundamentals to Applied Research acts as an invaluable reference book for fuel cell developers and students, researchers in industry entering the area of fuel cells and lecturers teaching fuel cells and hydrogen technology. Includes laboratory methods for fuel cell characterization and manufacture Outlines approaches in modelling components, cells and stacks Covers practical and theoretical methods for hydrogen production and storage

Fuel Cells: Technologies for Fuel Processing provides an overview of the most important aspects of fuel reforming to the generally interested reader, researcher, technologist, teacher, student, or engineer. The topics covered include all aspects of fuel reforming: fundamental chemistry, different modes of reforming, catalysts, catalyst deactivation, fuel desulfurization, reaction engineering, novel reforming concepts, thermodynamics, heat and mass transfer issues, system design, and recent research and development. While no attempt is made to describe the fuel cell itself, there is sufficient description of the fuel cell to show how it affects the fuel reformer. By focusing on the fundamentals, this book aims to be a source of information now and in the future. By avoiding time-sensitive information/analysis (e.g., economics) it serves as a single source of information for scientists and engineers in fuel processing technology. The material is presented in such a way that this book will serve as a reference for graduate level courses, fuel cell developers, and fuel cell researchers. Chapters written by experts in each area Extensive bibliography supporting each chapter Detailed index Up-to-date diagrams and full colour illustrations

This volume contains an archival record of the NATO Advanced Institute on Mini – Micro Fuel Cells – Fundamental and Applications held in Çesme – Izmir, Turkey, July 22–August 3, 2007. The ASIs are intended to be a high-level teaching activity in scientific and technical areas of current concern. In this volume, the reader may find interesting chapters on Mini- Micro Fuel Cells with fundamentals and applications. In recent years, fu- cell development, modeling and performance analysis has received much attention due to their potential for distributed power which is a critical issue for energy security and the environmental protection. Small fuel cells for portable applications are important for the security. The portable devices (many electronic and wireless) operated by fuel cells for providing all-day power, are very valuable for the security, for defense and in the war against terrorism. Many companies in NATO and non-NATO countries have concentrated to promote the fuel cell industry. Many universities with industrial partners committed to the idea of working together to develop fuel cells. As tech- logy advanced in the 1980s and beyond, many government organizations joined in spending money on fuel-cell research. In recent years, interest in using fuel cells to power portable electronic devices and other small equipment (cell phones, mobile phones, lab-tops, they are used as micro power source in biological applications) has increased partly due to the promise of fuel cells having higher energy density.

This new edition of Dr. Barbir's groundbreaking book still lays the groundwork for engineers, technicians and students better than any other resource, covering fundamentals of design, electrochemistry, heat and mass transport, as well as providing the context of system design and applications. Yet it now also provides invaluable information on the latest advances in modeling, diagnostics, materials, and components, along with an updated chapter on the evolving applications areas wherein PEM cells are being deployed."--pub. desc.

Including chemical, synthetic, and cross-disciplinary approaches; this book includes the necessary techniques and technologies to help readers better understand polymers for polymer electrolyte membrane (PEM) fuel cells. The methods in the book are essential to researchers and scientists in the field and will lead to further development in polymer and fuel cell technologies. • Provides complete, essential, and comprehensive overview of polymer applications for PEM fuel cells • Emphasizes state-of-the-art developments and methods, like PEMs for novel fuel cells and polymers for fuel cell catalysts • Includes detailed chapters on major topics, like PEM for direct liquid fuel cells and fluoropolymers and non-fluorinated polymers for PEM • Has relevance to a range of industries – like polymer engineering, materials, and green technology – involved with fuel cell technologies and R&D

Alcohol fuel cells are very attractive as power sources for mobile and portable applications. As they convert the chemical energy of fuels into electricity, much recent research is directed at developing suitable and efficient catalysts for the process. The present book focuses on pertinent types of nanomaterial-based catalysts, membranes and supports.

Electrochemical Power Sources (EPS) provides in a concise way the operational features, major types, and applications of batteries, fuel cells, and supercapacitors • Details the design, operational features, and applications of batteries, fuel cells, and supercapacitors • Covers improvements of existing EPSs and the development of new kinds of EPS as the results of intense R&D work • Provides outlook for future trends in fuel cells and batteries • Covers the most typical battery types, fuel cells and supercapacitors; such as zinc-carbon batteries, alkaline manganese dioxide batteries, mercury-zinc cells, lead-acid batteries, cadmium storage batteries, silver-zinc batteries and modern lithium batteries

This book introduces the reader to the state of the art in nanostructured anode and cathode electrocatalysts for low-temperature acid and alkaline fuel cells. It explores the electrocatalysis of anode (oxidation of organic molecules) and cathode (oxygen reduction) reactions. It also offers insights into metal-carbon interactions, correlating them with the catalytic activity of the electrochemical reactions. The book explores the electrocatalytic behaviour of materials based on noble metals and their alloys, as well as metal-metal oxides and metal-free nanostructures. It also discusses the surface and structural modification of carbon supports to enhance the catalytic activity of electrocatalysts for fuel-cell reactions.

This book provides a review of the latest advances in anion exchange membrane fuel cells. Starting with an introduction to the field, it then examines the chemistry and catalysis involved in this energy technology. It also includes an introduction to the mathematical modelling of these fuel cells before discussing the system design and performance of real-world systems. Anion exchange membrane fuel cells are an emerging energy technology that has the potential to overcome many of the obstacles of proton exchange membrane fuel cells in terms of the cost, stability, and durability of materials. The book is an essential reference resource for professionals, researchers, and policymakers around the globe working in academia, industry, and government.

Providing the reader with an up to date digest of the most important research currently carried out in the field, Electrochemistry Volume 14 is compiled and written by leading experts from across the globe. Coverage includes chapters on the use of metal organic frameworks as a precursor for electrocatalytic centre supports to enhance the oxygen reduction process in low temperature fuel cell systems, electrocatalysis for ethanol electrooxidation in alkaline media, and new polymer electrolyte and electrocatalysts for direct alcohol fuel cells. This volume is a key reference for researchers providing a timely overview of this exciting and developing area.