Carbon Based Nanomaterials for Advanced Thermal and Electrochemical Energy Storage and Conversion

Carbon Based Nanomaterials for Advanced Thermal and Electrochemical Energy Storage and Conversion presents a comprehensive overview of recent theoretical and experimental developments and prospects on carbon-based nanomaterials for thermal, solar and electrochemical energy conversion, along with their storage applications for both laboratory and industrial perspectives. Large growth in human populations has led to seminal growth in global energy consumption, hence fossil fuel usage has increased, as have unwanted greenhouse gases, including carbon dioxide, which results in critical environmental concerns. This book discusses this growing problem, aligning carbon nanomaterials as a solution because of their structural diversity and electronic, thermal and mechanical properties. Provides an overview on state-of-the-art carbon nanomaterials and key requirements for applications of carbon materials towards efficient energy storage and conversion Presents an updated and comprehensive review of recent work and the theoretical aspects on electrochemistry Includes discussions on the industrial production of carbon-based materials for energy applications, along with insights from industrial experts

This book presents state-of-the art synthetic techniques and applications for the use of carbon-based nanomaterials in energy conversion and storage. Fundamentals of synthesis and characterization are followed by descriptions of applications in solar cells (polymer, dye-sensitized, quantum dot, and transparent electrodes), thermoelectrics, fuel cells, supercapacitors, and lithium-based batteries. Storage and architecture of storage facilities for hydrogen and methane are also discussed.

Hybrid Atomic-Scale Interface Design for Materials Functionality covers a broad range of atomistic, meso and macro scale computational methodologies, including multiphase (hybrid) materials constructs for tailoring structural, thermal and electrical properties. As future materials are expected to perform with increasing efficiency in complex and dynamic environments hybrid materials design, in contrast to monolithic concepts, they are a cost-effective alternative. Taking materials hybridization at smaller scale, even at atomic scale, offers exceedingly high-payoff opportunities for optimizing materials functionality at reduced material consumption and even reduced qualification costs (eliminates many costly component and system level qualification tests). Presents computational methodologies for materials hybridization and interface design at the atomic scale Covers materials interface design (atomic configuration), a key component to optimize and achieve performance metrics Helps readers with material selectivity and in the materials design phase of any product design

Carbon nanotubes are rolled up graphene sheets with a quasi-one-dimensional structure of nanometer-scale diameter. In these last twenty years, carbon nanotubes have attracted much attention from physicists, chemists, material scientists, and electronic device engineers, because of their excellent structural, electronic, optical, chemical and mechanical properties. More recently, demand for innovative industrial applications of carbon nanotubes is increasing. This book covers recent research topics regarding syntheses techniques of carbon nanotubes and nanotube-based composites, and their applications. The chapters in this book will be helpful to many students, engineers and researchers working in the field of carbon nanotubes.

Fluorinated Materials for Energy Conversion offers advanced information on the application of fluorine chemistry to energy conversion materials for lithium batteries, fuel cells, solar cells and so on. Fluorine compounds and fluorination techniques have recently gained important roles in improving the electrochemical characteristics of such energy production devices. The book therefore focuses on new batteries with high performance, the improvements of cell performance and the improvement of electrode and cell characteristics. The authors present new information on the effect of fluorine and how to make use of fluorination techniques and fluorine compounds. With emphasis on recent developments, this book is suitable for students, researchers and engineers working in chemistry, materials science and electrical engineering. Contains practical information, supported by examples Provides an update on recent developments in the field Written by specialists working in fluorine chemistry, electrochemistry, polymer and solid state chemistry

This thesis focuses on the synthesis and characterization of various carbon allotropes (e.g., graphene oxide/graphene, graphene foam (GF), GF/carbon nanotube (CNT) hybrids) and their composites for electrochemical energy storage applications. The coverage ranges from materials synthesis to electrochemical analysis, to state-of-the-art electrochemical energy storage devices, and demonstrates how electrochemical characterization techniques can be integrated and applied in the active materials selection and nanostructure design process. Readers will also discover the latest findings on graphene-based electrochemical energy storage devices including asymmetric supercapacitors, lithium ion batteries and flexible Ni/Fe batteries. Given the unique experimental procedures and methods, the systematic electrochemical analysis, and the creative flexible energy storage device design presented, the thesis offers a valuable reference guide for researchers and newcomers to the field of carbon-based electrochemical energy storage.

Carbon Nanomaterials: Modeling, Design, and Applications provides an in-depth review and analysis of the most popular carbon nanomaterials, including fullerenes, carbon nanotubes, graphene and novel carbon nanomaterial-based membranes and thin films, with emphasis on their modeling, design and applications. This book provides basic knowledge of the structures, properties and applications of carbon-based nanomaterials. It illustrates the fundamental structure-property relationships of the materials in both experimental and modeling aspects, offers technical guidance in computational simulation of nanomaterials, and delivers an extensive view on current achievements in research and practice, while presenting new possibilities in the design and usage of carbon nanomaterials. This book is aimed at both undergraduate and graduate students, researchers, designers, professors, and professionals within the fields of materials science and engineering, mechanical engineering, applied physics, and chemical engineering.

Energy storage devices are considered to be an important field of interest for researchers worldwide. Batteries and supercapacitors are therefore extensively studied and progressively evolving. The book not only emphasizes the fundamental theories, electrochemical mechanism and its computational view point, but also discusses recent developments in electrode designing based on nanomaterials, separators, fabrication of advanced devices and their performances.

Emerging Materials for Energy Conversion and Storage presents the state-of-art of emerging materials for energy conversion technologies (solar cells and fuel cells) and energy storage technologies (batteries, supercapacitors and hydrogen storage). The book is organized into five primary sections, each with three chapters authored by worldwide experts in the fields of materials science, physics, chemistry and engineering. It covers the fundamentals, functionalities, challenges and prospects of different classes of emerging materials, such as wide bandgap semiconductors, oxides, carbon-based nanostructures, advanced ceramics, chalcogenide nanostructures, and flexible organic electronics nanomaterials. The book is an important reference for students and researchers (from academics, but also industry) interested in understanding the properties of emerging materials. Explores the fundamentals, challenges and prospects for the application of emerging materials in the development of energy conversion and storage devices Presents a discussion of solar cell and photovoltaic, fuel cell, battery electrode, supercapacitor and hydrogen storage applications Includes notable examples of energy devices based on emerging materials to illustrate recent advances in this field

The use of nanomaterials in energy conversion and storage represents an opportunity to improve the performance, density and ease of transportation in renewable resources. This book looks at the most recent research on the topic, with particular focus on artificial photosynthesis and lithium-ion batteries as the most promising technologies to date. Research on the broad subject of energy conversion and storage calls for expertise from a wide range of backgrounds, from the most fundamental perspectives of the key catalytic processes at the molecular level to device scale engineering and optimization. Although the nature of the processes dictates that electrochemistry is a primary characterization tool, due attention is given to advanced techniques such as synchrotron studies in operando. These studies look at the gap between the performance of current technology and what is needed for the future, for example how to improve on the lithium-ion battery and to go beyond its capabilities. Suitable for students and practitioners in the chemical, electrochemical, and environmental sciences, Nanomaterials for Energy Conversion and Storage provides the information needed to find scalable, economically viable and safe solutions for sustainable energy. Contents: The Principle of Photoelectrochemical Water Splitting (Peiyan Ma and Dunwei Wang)Semiconducting Photocatalysis for Solar Hydrogen Conversion (Shaohua Shen and Jie Chen)Visible-Light-Driven Photocatalysis (Qingzhe Zhang, Yanlong Liu, Zhenhe Xu, Yue Zhao, Mohamed Chaker and Dongling Ma)Metal-Nitride Nanostructures: Emerging Catalysts for Artificial Photosynthesis (Md Golam Kibria, Bandar AlOtaibi and Zetian Mi)Surface Engineering of Semiconductors for Photoelectrochemical Water Splitting (Gongming Wang, Yi Yang and Yat Li)Photoanodic and Photocathodic Materials Applied for Free-Running Solar Water Splitting Devices (Miao Zhong, Hiroyuki Kaneko, Taro Yamada and Kazunari Domen)Electrocatalytic Processes in Energy Technologies (Yang Huang, Min Zeng, Qiufang Gong and Yanguang Li)Soft X-Ray Spectroscopy on Photocatalysis (Yi-Sheng Liu, Cheng-Hao Chuang and Jinghua Guo)Photoelectrochemical Tools for the Assessment of Energy Conversion Devices (Isaac Herraiz-Cardona and Sixto Gimenez)Fundamentals of Rechargable Batteries and Electrochemical Potentials of Electrode Materials (Chaofeng Liu and Guozhong Cao)Revitalized Interest in Vanadium Pentoxide as Cathode Material for Alkali-Ion Batteries (Yanwei Li, Jinhuan Yao, Robert C Massé, Evan Uchaker and Guozhong Cao)Tin-Based Compounds as Anode Materials for Lithium-Ion Storage (Ming Zhang and Guozhong Cao)Beyond Li-Ion: Electrode Materials for Sodium- and Magnesium-Ion Batteries (Robert Massé, Evan Uchaker and Guozhong Cao)Nanomaterials and Nanostructures for Regulating Ions and Electron Transport in Advanced Energy Storage Devices (Yu Wang and Wei-Hong Zhong) Readership: Students, researchers and practitioners in the chemical, electrochemical, and environmental sciences. Keywords: Nanomaterials;Lithium-Ion Batteries;Electrochemistry;Energy Conversion;Energy Storage;Artificial PhotosynthesisReview:0

Carbon-Based Polymer Nanocomposites for Environmental and Energy Applications provides the fundamental physico-chemical characterizations of recently explored carbon-based polymer nanocomposites, such as carbon nanotubes, graphene and its derivatives, nanodiamond, fullerenes and other nano-sized carbon allotropes. The book also covers the applications of carbon-based polymer nanocomposite in the environmental and energy fields. Topics range from the various approaches that have been explored and developed for the fabrication of carbon-based polymer nanocomposite, to their applications in tackling environmental and energy related issues. Provides a clear picture of the current state-of-the-art and future trends in carbon-based polymer nanomaterials Explains the interactions between nanofiller-polymer matrices and mechanisms related to applications in environmental pollution and energy shortage Includes computational and experimental studies of the physical and chemical properties of carbon-based polymer nanocomposites Features chapters written by world leading experts

Offering comprehensive coverage of this hot topic, this two-volume handbook and ready reference treats a wide range of important aspects, from synthesis and catalytic properties of carbon materials to their applications as metal-free catalysts in various important reactions and industrial processes. Following a look at recent advances in the development of carbon materials as carbon-based metal-free catalysts, subsequent sections deal with a mechanistic understanding for the molecular design of efficient carbon-based metal-free catalysts, with a special emphasis on heteroatom-doped carbon nanotubes, graphene, and graphite. Examples of important catalytic processes covered include clean energy conversion and storage, environmental protection, and synthetic chemistry. With contributions from world-leading scientists, this is an indispensable source of information for academic and industrial researchers in catalysis, green chemistry, electrochemistry, materials science, nanotechnology, energy technology, and chemical engineering, as well as graduates and scientists entering the field.

The book sets the standard on carbon materials for electrode design. For the first time, the leading experts in this field summarize the preparation techniques and specific characteristics together with established and potential applications of the different types of carbon-based electrodes. An introductory chapter on the properties of carbon together with chapters on the electrochemical characteristics and properties of the different modifications of carbon such as carbon nanotubes, graphene, carbon fiber, diamond or highly ordered pyrolytic graphite provide the reader with the basics on this fascinating and ubiquitous electrode material. Cutting-edge technologies such as carbon electrodes in efficient supercapacitors, Li-ion batteries and fuel cells, or electrodes prepared by screen-printing are discussed, giving a complete but concise overview about the topic. The clearly structured book helps newcomers to grasp easily the principles of carbon-based electrodes, while researchers in fundamental and applied electrochemistry will find new ideas for further research on related key technologies.

This book provides an authoritative source of information on the use of nanomaterials to enhance the performance of existing electrochemical energy storage systems and the manners in which new such systems are being made possible. The book covers the state of the art of the design, preparation, and engineering of nanoscale functional materials as effective catalysts and as electrodes for electrochemical energy storage and mechanistic investigation of electrode reactions. It also provides perspectives and challenges for future research. A related book by the same editors is: Nanomaterials for Fuel Cell Catalysis.

Bioremediation refers to the clean‐up of pollution in soil, groundwater, surface water, and air using typically microbiological processes. It uses naturally occurring bacteria and fungi or plants to degrade, transform or detoxify hazardous substances to human health or the environment. For bioremediation to be effective, microorganisms must enzymatically attack the pollutants and convert them to harmless products. As bioremediation can be effective only where environmental conditions permit microbial growth and action, its application often involves the management of ecological factors to allow microbial growth and degradation to continue at a faster rate. Like other technologies, bioremediation has its limitations. Some contaminants, such as chlorinated organic or high aromatic hydrocarbons, are resistant to microbial attack. They are degraded either gradually or not at all, hence, it is not easy to envisage the rates of clean-up for bioremediation implementation. Bioremediation represents a field of great expansion due to the important development of new technologies. Among them, several decades on metagenomics expansion has led to the detection of autochthonous microbiota that plays a key role during transformation. Transcriptomic guides us to know the expression of key genes and proteomics allow the characterization of proteins that conduct specific reactions. In this book we show specific technologies applied in bioremediation of main interest for research in the field, with special attention on fungi, which have been poorly studied microorganisms. Finally, new approaches in the field, such as CRISPR-CAS9, are also discussed. Lastly, it introduces management strategies, such as bioremediation application for managing affected environment and bioremediation approaches. Examples of successful bioremediation applications are illustrated in radionuclide entrapment and retardation, soil stabilization and remediation of polycyclic aromatic hydrocarbons, phenols, plastics or fluorinated compounds. Other emerging bioremediation methods include electro bioremediation, microbe-availed phytoremediation, genetic recombinant technologies in enhancing plants in accumulation of inorganic metals, and metalloids as well as degradation of organic pollutants, protein-metabolic engineering to increase bioremediation efficiency, including nanotechnology applications are also discussed.

Unique in providing an overview of the subject on the scientific level, this book presents the current state of the art with regard to different aspects of sustainable energy production and its efficient storage. The broad scope ranges from nanomaterials for energy production, via fuel cells and nanostructured materials for fuel production, right up to supercapacitors and climate change. Edited by a rising star within the community, this is an invaluable work on a hot topic for materials scientists, solid state, surface and physical chemists, as well as those chemists working in industry and chemical engineers.

This book comprehensively describes the fundamentals of electrochemical water electrolysis as well as the latest materials and technological developments. It addresses a variety of topics such as electrochemical processes, materials, components, assembly and manufacturing, and degradation mechanisms, as well as challenges and strategies. It also includes an understanding of how materials and technologies for electrochemical water electrolysis have developed in recent years, and it describes the progress in improving performance and providing benefits to energy systems and applications. Features the most recent advances in electrochemical water electrolysis to produce hydrogen Discusses cutting-edge materials and technologies for electrochemical water electrolysis Includes both experimental and theoretical approaches that can be used to guide and promote materials as well as technological development for electrochemical water electrolysis Comprises work from international leading scientists active in electrochemical energy and environmental research and development Provides invaluable information that will benefit readers from both academia and industry With contributions from researchers at the top of their fields, the book includes in-depth discussions covering the engineering of components and applied devices, making this an essential read for scientists and engineers working in the development of electrochemical energy devices and related disciplines.

Carbon Nanotubes and Graphene is a timely second edition of the original Science and Technology of Carbon Nanotubes. Updated to include expanded coverage of the preparation, purification, structural characterization, and common application areas of single- and multi-walled CNT structures, this work compares, contrasts, and, where appropriate, unitizes CNT to graphene. This much expanded second edition reference supports knowledge discovery, production of impactful carbon research, encourages transition between research fields, and aids the formation of emergent applications. New chapters encompass recent developments in the theoretical treatments of electronic and vibrational structures, and magnetic, optical, and electrical solid-state properties, providing a vital base to research. Current and potential applications of both materials, including the prospect for large-scale synthesis of graphene, biological structures, and flexible electronics, are also critically discussed. Updated discussion of properties, structure, and morphology of biological and flexible electronic applications aids fundamental knowledge discovery Innovative parallel focus on nanotubes and graphene enables you to learn from the successes and failures of, respectively, mature and emergent partner research disciplines High-quality figures and tables on physical and mathematical applications expertly summarize key information – essential if you need quick, critically relevant data

Todays chemical industry processes worldwide largely depend on catalytic reactions and the desirable future evolution of this industry toward more selective products, more environmentally friendly products, more energy-efficient processes, a smaller use of hazardous reagents, and a better use of raw materials also largely involves the development of better catalysts and, specifically, purposely designed catalytic materials. The careful study and development of the new-generation catalysts involve relatively large groups of specialists in universities, research centers, and industries, joining forces from different scientific and technical disciplines. This book has put together recent, state-of-the-art topics on current trends in catalytic materials and consists of 16 chapters.