Alkene Polymerization Reactions with Transition Metal Catalysts

Alkene Polymerization Reactions with Transition Metal Catalysts
Author: Yury Kissin
Publsiher: Elsevier
Total Pages: 495
Release: 2008-03-10
ISBN 10: 9780080557991
ISBN 13: 0080557996
Language: EN, FR, DE, ES & NL

Alkene Polymerization Reactions with Transition Metal Catalysts Book Review:

During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent several major changes: 1. The list of commercial heterogeneous Ziegler-Natta catalysts for the synthesis of polyethylene and stereoregular polyolefins was completely renewed affording an unprecedented degree of control over the polymer structure. 2. Research devoted to metallocene and other soluble transition-metal catalysis has vastly expanded and has shifted toward complexes of transition metals with multidentate ligands. 3. Recent developments in gel permeation chromatography, temperature-rising fractionation, and crystallization fractionation provided the first reliable information about differences between various active centers in transition-metal catalysts. 4. A rapid development of high-resolution 13C NMR spectroscopy resulted in greatly expanded understanding of the chemical and steric features of polyolefins and alkene copolymers. These developments require a new review of all aspects of alkene polymerization reactions with transition-metal catalysts. The first chapter in the book is an introductory text for researchers who are entering the field. It describes the basic principles of polymerization reactions with transition-metal catalysts, the types of catalysts, and commercially manufactured polyolefins. The next chapter addresses the principal issue of alkene polymerization catalysis: the existence of catalyst systems with single and multiple types of active centers. The subsequent chapters are devoted to chemistry and stereochemistry of elemental reaction steps, structures of catalyst precursors and reactions leading to the formation of active centers, kinetics of polymerization reactions, and their mechanisms. The book describes the latest commercial polymerization catalysts for the synthesis of polyethylenes and polypropylene The book provides a detailed description of the multi-center nature of commercial Ziegler-Natta catalysts. The book devotes specialized chapters to the most important aspects of transition metal polymerization catalysts: the reactions leading to the formation of active centers, the chemistry and stereochemistry of elemental polymerization steps, reaction kinetics, and the polymerization mechanism. The book contains an introductory chapter for researchers who are entering the field of polymerization catalysis. It describes the basic principles of polymerization reactions with transition-metal catalysts and the types of commercially manufactured polyolefins and copolymers The book contains over 2000 references, the most recent up to end of 2006.

Handbook of Transition Metal Polymerization Catalysts

Handbook of Transition Metal Polymerization Catalysts
Author: Ray Hoff,Robert T. Mathers
Publsiher: John Wiley & Sons
Total Pages: 640
Release: 2010-09-16
ISBN 10: 9780470504420
ISBN 13: 0470504420
Language: EN, FR, DE, ES & NL

Handbook of Transition Metal Polymerization Catalysts Book Review:

A one-stop resource for understanding and applying polymerization catalysts An edited volume featuring contributions from leading researchers, the Handbook of Transition Metal Polymerization Catalysts covers the design and synthesis of catalysts, and their applications in synthesis of polymers. Dealing with those polymerization catalysts that afford commercially acceptable yields of polymer with respect to catalyst mass and promising newer catalysts, this practical reference provides polymer and organic chemists with a comprehensive overview of the known methods for developing and applying these important catalysts. With both recent advances and historically important catalysts, the subjects covered in this text include: Metal alkyls and other compounds that function as co-catalysts with a large number of catalysts The varieties of porous silica either necessary or valuable in certain catalyst formulations Catalyst scale-up and commercialization Copper catalysts for olefin polymerization Morphology control Along with the above topics, the Handbook of Transition Metal Polymerization Catalysts provides tables of valuable data to assist in reproducing a synthesis or applying the knowledge to a new problem. Polymerization reactivities, polymer properties, monomer and solvent purity requirements, molecular weights, distribution, and reactivity ratios are also covered. The Handbook of Transition Metal Polymerization Catalysts offers an excellent one-stop resource for understanding and applying polymerization catalysts.

Late Transition Metal Polymerization Catalysis

Late Transition Metal Polymerization Catalysis
Author: Bernhard Rieger,Lisa Saunders Baugh,Smita Kacker,Susanne Striegler
Publsiher: John Wiley & Sons
Total Pages: 345
Release: 2006-03-06
ISBN 10: 3527605266
ISBN 13: 9783527605262
Language: EN, FR, DE, ES & NL

Late Transition Metal Polymerization Catalysis Book Review:

At the start of the 1950s, Ziegler and Natta discovered that simple metallorganic catalysts are capable of transforming olefins into linear polymers with highly ordered structures. This pioneering discovery was recognized with a Nobel Prize in 1963. In the 80s and 90s, the development of molecular defined metallocenes led to a renaissance for non-polar polyolefin materials. Designer catalysts allowed a greater precision in defining properties of the material. The past 10 years have seen the discovery of new catalysts based on late transition metals, which allow the combination of polar monomers with non-polar olefins and thus lead to innovative materials. Here, the world's leading authors from industry and academia describe the latest developments in this fascinating field for the first time in such comprehensive detail. In so doing, they introduce readers systematically to the basic principles and show how these new catalysts can effectively be used for polymerization reactions. This makes the book an ideal and indispensable reference for specialists, advanced students, and scientists of various disciplines dealing with research into catalysts and materials science.

Carraher s Polymer Chemistry Ninth Edition

Carraher s Polymer Chemistry  Ninth Edition
Author: Charles E. Carraher Jr.
Publsiher: CRC Press
Total Pages: 818
Release: 2013-09-05
ISBN 10: 1466552034
ISBN 13: 9781466552036
Language: EN, FR, DE, ES & NL

Carraher s Polymer Chemistry Ninth Edition Book Review:

Most of the advancements in communication, computers, medicine, and air and water purity are linked to macromolecules and a fundamental understanding of the principles that govern their behavior. These fundamentals are explored in Carraher's Polymer Chemistry, Ninth Edition. Continuing the tradition of previous volumes, the latest edition provides a well-rounded presentation of the principles and applications of polymers. With an emphasis on the environment and green chemistry and materials, this edition offers detailed coverage of natural and synthetic giant molecules, inorganic and organic polymers, biomacromolecules, elastomers, adhesives, coatings, fibers, plastics, blends, caulks, composites, and ceramics. Using simple fundamentals, this book demonstrates how the basic principles of one polymer group can be applied to all of the other groups. It covers reactivities, synthesis and polymerization reactions, techniques for characterization and analysis, energy absorption and thermal conductivity, physical and optical properties, and practical applications. This edition includes updated techniques, new sections on a number of copolymers, expanded emphasis on nanotechnology and nanomaterials, and increased coverage of topics including carbon nanotubes, tapes and glues, photochemistry, and more. With topics presented so students can understand polymer science even if certain parts of the text are skipped, this book is suitable as an undergraduate as well as an introductory graduate-level text. The author begins most chapters with theory followed by application, and generally addresses the most critical topics first. He provides all of the elements of an introductory text, covering synthesis, properties, applications, and characterization. This user-friendly book also contains definitions, learning objectives, questions, and additional reading in each chapter.

Activation Of Alkenes And Alkynes

Activation Of Alkenes And Alkynes
Author: M.M. Taqui Khan
Publsiher: Elsevier
Total Pages: 208
Release: 2012-12-02
ISBN 10: 0323160166
ISBN 13: 9780323160162
Language: EN, FR, DE, ES & NL

Activation Of Alkenes And Alkynes Book Review:

Homogeneous Catalysis by Metal Complexes, Volume II: Activation of Alkenes and Alkynes reviews and systematizes the chemistry of metal ion activation of alkenes and alkynes. The book presents the migration of ? bonds; the oxo reaction; and the hydrosilation of alkenes and alkynes. The text also covers topics on the oxidation of alkenes and alkynes, as well as the multiple insertion reactions of alkenes and alkynes.

Organometallic Chemistry

Organometallic Chemistry
Author: M. Green
Publsiher: Royal Society of Chemistry
Total Pages: 504
Release: 2005
ISBN 10: 0854043438
ISBN 13: 9780854043439
Language: EN, FR, DE, ES & NL

Organometallic Chemistry Book Review:

This Specialist Periodical Report aims to reflect the growing interest in the potential of organometallic chemistry.

Handbook of Transition Metal Polymerization Catalysts

Handbook of Transition Metal Polymerization Catalysts
Author: Ray Hoff
Publsiher: John Wiley & Sons
Total Pages: 768
Release: 2018-05-08
ISBN 10: 1119242134
ISBN 13: 9781119242130
Language: EN, FR, DE, ES & NL

Handbook of Transition Metal Polymerization Catalysts Book Review:

Including recent advances and historically important catalysts, this book overviews methods for developing and applying polymerization catalysts – dealing with polymerization catalysts that afford commercially acceptable high yields of polymer with respect to catalyst mass or productivity. • Contains the valuable data needed to reproduce syntheses or use the catalyst for new applications • Offers a guide to the design and synthesis of catalysts, and their applications in synthesis of polymers • Includes the information essential for choosing the appropriate reactions to maximize yield of polymer synthesized • Presents new chapters on vanadium catalysts, Ziegler catalysts, laboratory homopolymerization, and copolymerization

Comprehensive Organometallic Chemistry III

Comprehensive Organometallic Chemistry III
Author: Robert Crabtree
Publsiher: Anonim
Total Pages: 9000
Release: 2007
ISBN 10:
ISBN 13: STANFORD:36105122424513
Language: EN, FR, DE, ES & NL

Comprehensive Organometallic Chemistry III Book Review:

Comprehensive Organometallic Chemistry, (COMC-III), Third Edition, 13 Volume Set is aimed at the specialist and non-specialist alike. It covers the major developments in the field in a carefully presented way with extensive cross-references. COMC-III provides a clear and comprehensive overview of developments since 1993 and attempts to predict trends in the field over the next ten years. Applications of organometallic chemistry continue to expand and this has been reflected by the significant increase in the number of volumes devoted to applications in COMC-III. Organic chemists have edited the volumes on organometallic chemistry towards organic synthesis - this is now organized by reaction type so as to be readily accessible to the organic community. Like its predecessors, COMC (1982) and COMC-II (1995), this new work is the essential reference text for any chemist or technologist who needs to use or apply organometallic compounds. Also available online via ScienceDirect (2006) - featuring extensive browsing, searching, and internal cross-referencing between articles in the work, plus dynamic linking to journal articles and abstract databases, making navigation flexible and easy. For more information, pricing options and availability visit www.info.sciencedirect.com. Presents a comprehensive overview of the major developments in the field since 1993 providing general and significant insights Highlights the expansion of applications in organometallic chemistry with a strong organic synthesis focus Provides a structured first point of entry to the key literature and background material for those planning research, teaching and writing about the area

Transition Metals and Organometallics as Catalysts for Olefin Polymerization

Transition Metals and Organometallics as Catalysts for Olefin Polymerization
Author: Walter Kaminsky,Hansjörg Sinn
Publsiher: Springer Science & Business Media
Total Pages: 442
Release: 2012-12-06
ISBN 10: 3642832768
ISBN 13: 9783642832765
Language: EN, FR, DE, ES & NL

Transition Metals and Organometallics as Catalysts for Olefin Polymerization Book Review:

More than 30 years after the discovery of transition metals and organometal lics as catalysts for olefin polymerization these catalysts did not have lost their fascination. Since 1953 when Karl Ziegler has discovered the catalytic polymerization of ethylene leading to plastically formable polymers which are mechanically stable up to temperatures of about 100°C, synthetic polymers and rubbers have made their way right into private houses. This discovery has been a main impetus for the fast growing production of plastics. The stereoselective poly merization of propylene and other long-chain a-olefins first detected by Giulio Natta leads to an even broadened field of applications. Another enforcing factor were the developments of Standard Oil of Indiana and Phillipps Petroleum Company who engaged in the polymerization of a-olefins supported molybdenum, cobalt and later on chromium catalysts which clearly indicates the wide variety of suitable systems. This kind of research acknowledged merit when in 1963 the Nobel prize of chemistry was awarded to Ziegler and Natta. Although to a great extent there is a technical application for these catalysts, up to now the nature of the active centres and many reaction mechanisms are not completely known.

Palladium Catalyzed Modification of Nucleosides Nucleotides and Oligonucleotides

Palladium Catalyzed Modification of Nucleosides  Nucleotides and Oligonucleotides
Author: Anant R. Kapdi,Debabrata Maiti,Yogesh S. Sanghvi
Publsiher: Elsevier
Total Pages: 358
Release: 2018-06-04
ISBN 10: 012811293X
ISBN 13: 9780128112939
Language: EN, FR, DE, ES & NL

Palladium Catalyzed Modification of Nucleosides Nucleotides and Oligonucleotides Book Review:

Palladium-Catalyzed Modification of Nucleosides, Nucleotides and Oligonucleotides describes the procedures and protocols related to the modification of nucleosides, nucleotides and oligonucleotides via Pd-mediated cross-coupling processes. The book highlights the growing area of nucleic acid modification and how Pd-mediated coupling reactions can assist this development. Users will find key synthetic protocols for these reactions in this latest volume in the Latest Trends in Palladium Chemistry series. As most of the research in the field of antiviral agents has centered on the use of modified nucleosides that have exhibited promising activity, this book provides an up-to-date reference for both professionals in industry and other interested parties. Provides synthetic routes for useful nucleoside molecules, information otherwise found only through time-consuming literature searches Covers metal-mediated and metal-catalyzed cross coupling processes of nucleosides and related compounds Includes Suzuki-Miyaura, Stille and Sonogashira reactions, as well as C-H bond functionalization Highlights the growing area of nucleic acid modification and how Pd-mediated coupling reactions can assist

Monitoring Polymerization Reactions

Monitoring Polymerization Reactions
Author: Wayne F. Reed,Alina M. Alb
Publsiher: John Wiley & Sons
Total Pages: 488
Release: 2013-12-02
ISBN 10: 1118733975
ISBN 13: 9781118733974
Language: EN, FR, DE, ES & NL

Monitoring Polymerization Reactions Book Review:

Offers new strategies to optimize polymer reactions With contributions from leading macromolecular scientists and engineers, this book provides a practical guide to polymerization monitoring. It enables laboratory researchers to optimize polymer reactions by providing them with a better understanding of the underlying reaction kinetics and mechanisms. Moreover, it opens the door to improved industrial-scale reactions, including enhanced product quality and reduced harmful emissions. Monitoring Polymerization Reactions begins with a review of the basic elements of polymer reactions and their kinetics, including an overview of stimuli-responsive polymers. Next, it explains why certain polymer and reaction characteristics need to be monitored. The book then explores a variety of practical topics, including: Principles and applications of important polymer characterization tools, such as light scattering, gel permeation chromatography, calorimetry, rheology, and spectroscopy Automatic continuous online monitoring of polymerization (ACOMP) reactions, a flexible platform that enables characterization tools to be employed simultaneously during reactions in order to obtain a complete record of multiple reaction features Modeling of polymerization reactions and numerical approaches Applications that optimize the manufacture of industrially important polymers Throughout the book, the authors provide step-by-step strategies for implementation. In addition, ample use of case studies helps readers understand the benefits of various monitoring strategies and approaches, enabling them to choose the best one to match their needs. As new stimuli-responsive and "intelligent" polymers continue to be developed, the ability to monitor reactions will become increasingly important. With this book as their guide, polymer scientists and engineers can take full advantage of the latest monitoring strategies to optimize reactions in both the lab and the manufacturing plant.

Homogeneous Catalysis with Compounds of Rhodium and Iridium

Homogeneous Catalysis with Compounds of Rhodium and Iridium
Author: R. Dickson
Publsiher: Springer Science & Business Media
Total Pages: 278
Release: 1985-09-30
ISBN 10: 9789027718808
ISBN 13: 9027718806
Language: EN, FR, DE, ES & NL

Homogeneous Catalysis with Compounds of Rhodium and Iridium Book Review:

Some years ago, I agreed to contribute a volume to the Academic Press 'Organo metallic Chemistry' series - the metals to be covered were rhodium and iridium. Initially, my plan was to discuss both the fundamental organometallic chemistry and applications in organic synthesis. When the first draft of the manuscript was complete, it was apparent that I had exceeded my allowance of pages by a huge amount. It was then that I decided that the catalysis section warranted separate treatment. I am grateful to Reidel for agreeing to publish this volume on Homogeneous Catalysis with Compounds of Rhodium and Iridium as part of their 'Catalysis by Metal Complexes' series. The material I had for the original Academic Press project covered the litera ture to the end of 1978. I decided to update this to the end of 1982 with a few key references from 1983. It is some measure of the rate of progress in this field that the number of references almost doubled during this revision.

Organometallic Chemistry

Organometallic Chemistry
Author: E. W. Abel,F. G. A. Stone
Publsiher: Royal Society of Chemistry
Total Pages: 464
Release: 1978
ISBN 10: 0851865518
ISBN 13: 9780851865515
Language: EN, FR, DE, ES & NL

Organometallic Chemistry Book Review:

This Specialist Periodical Report aims to reflect the growing interest in the potential of organometallic chemistry.

Science of Synthesis Houben Weyl Methods of Molecular Transformations Vol 7

Science of Synthesis  Houben Weyl Methods of Molecular Transformations Vol  7
Author: Anonim
Publsiher: Georg Thieme Verlag
Total Pages: 802
Release: 2014-06-11
ISBN 10: 3131779616
ISBN 13: 9783131779618
Language: EN, FR, DE, ES & NL

Science of Synthesis Houben Weyl Methods of Molecular Transformations Vol 7 Book Review:

Science of Synthesis provides a critical review of the synthetic methodology developed from the early 1800s to date for the entire field of organic and organometallic chemistry. As the only resource providing full-text descriptions of organic transformations and synthetic methods as well as experimental procedures, Science of Synthesis is therefore a unique chemical information tool. Over 1000 world-renowned experts have chosen the most important molecular transformations for a class of organic compounds and elaborated on their scope and limitations. The systematic, logical and consistent organization of the synthetic methods for each functional group enables users to quickly find out which methods are useful for a particular synthesis and which are not. Effective and practical experimental procedures can be implemented quickly and easily in the lab. // The content of this e-book was originally published in July 2004.

Science of Synthesis Houben Weyl Methods of Molecular Transformations Vol 2

Science of Synthesis  Houben Weyl Methods of Molecular Transformations Vol  2
Author: Tsuneo Imamoto
Publsiher: Georg Thieme Verlag
Total Pages: 1070
Release: 2014-05-14
ISBN 10: 313177911X
ISBN 13: 9783131779113
Language: EN, FR, DE, ES & NL

Science of Synthesis Houben Weyl Methods of Molecular Transformations Vol 2 Book Review:

Science of Synthesis provides a critical review of the synthetic methodology developed from the early 1800s to date for the entire field of organic and organometallic chemistry. As the only resource providing full-text descriptions of organic transformations and synthetic methods as well as experimental procedures, Science of Synthesis is therefore a unique chemical information tool. Over 1000 world-renowned experts have chosen the most important molecular transformations for a class of organic compounds and elaborated on their scope and limitations. The systematic, logical and consistent organization of the synthetic methods for each functional group enables users to quickly find out which methods are useful for a particular synthesis and which are not. Effective and practical experimental procedures can be implemented quickly and easily in the lab. // The content of this e-book was originally published in October 2002.

Homogeneous Catalysis by Metal Complexes Activation of alkenes and alkynes

Homogeneous Catalysis by Metal Complexes  Activation of alkenes and alkynes
Author: M. M. Taqui Khan,Arthur Earl Martell
Publsiher: Anonim
Total Pages: 195
Release: 1974
ISBN 10:
ISBN 13: UOM:39076006404128
Language: EN, FR, DE, ES & NL

Homogeneous Catalysis by Metal Complexes Activation of alkenes and alkynes Book Review:

Band 2.

Early Main Group Metal Catalysis

Early Main Group Metal Catalysis
Author: Sjoerd Harder
Publsiher: John Wiley & Sons
Total Pages: 400
Release: 2020-02-03
ISBN 10: 3527344489
ISBN 13: 9783527344482
Language: EN, FR, DE, ES & NL

Early Main Group Metal Catalysis Book Review:

Early Main Group Metal Catalysis gives a comprehensive overview of catalytic reactions in the presence of group 1 and group 2 metals. Chapters are ordered to reaction type, contain educational elements and deal with concepts illustrated by examples that cover the main developments. After a short introduction on polar organometallic chemistry and synthesis of early main group metal complexes, a variety of catalytic reactions are described, e.g. polymerization of alkenes, hydroamination and phosphination reactions, hydrosilylation, hydroboration and hydrogenation catalysis, as well as enantioselective and Lewis-acid catalysis. The book addresses organic chemists and researchers in industry interested in the state-of-the-art and new possibilities of early main group metal catalysis as well as newcomers to the field. Written by a team of leaders in the field, it is a very welcome addition to the area of main group metal chemistry, and to the field of catalysis.

Metalorganic Catalysts for Synthesis and Polymerization

Metalorganic Catalysts for Synthesis and Polymerization
Author: Walter Kaminsky
Publsiher: Springer Science & Business Media
Total Pages: 674
Release: 2012-12-06
ISBN 10: 3642601782
ISBN 13: 9783642601781
Language: EN, FR, DE, ES & NL

Metalorganic Catalysts for Synthesis and Polymerization Book Review:

45 years after the discovery of transition metals and organometallics as cocatalysts for the polymerization of olefins and for organic synthesis, these compounds have not lost their fascination. The birthday of Karl Ziegler, the great pioneer in this metalorganic catalysis, is now 100 years ago. Polyolefins and polydienes produced by Ziegler-Natta catalysis are the most important plastics and elastomers. New impulses for the polymerization of olefins have been brought about by highly active metallocenes and other single site catalysts. Just by changing the ligands of the organometallic compounds, the structure of the polymers produced can be tailored in a wide manner. In invited lectures and posters, relevant aspects of the metalorganic catalysts for synthesis and polymerization are discussed in this book. This includes mechanism and kinetics, stereochemistry, material properties, and industrial applications.

Introduction to Polymer Chemistry Second Edition

Introduction to Polymer Chemistry  Second Edition
Author: Charles E. Carraher Jr.
Publsiher: CRC Press
Total Pages: 510
Release: 2010-01-12
ISBN 10:
ISBN 13: UCSD:31822037486834
Language: EN, FR, DE, ES & NL

Introduction to Polymer Chemistry Second Edition Book Review:

With an emphasis on the environment and green chemistry and materials, this second edition offers detailed coverage of natural and synthetic giant molecules, inorganic and organic polymers, elastomers, adhesives, coatings, fibers, plastics, ceramics, and more.

Inorganic Reactions and Methods Formation of bonds to transition and inner transition metals

Inorganic Reactions and Methods  Formation of bonds to transition and inner transition metals
Author: Anonim
Publsiher: Anonim
Total Pages: 329
Release: 1986
ISBN 10:
ISBN 13: UCLA:L0078749975
Language: EN, FR, DE, ES & NL

Inorganic Reactions and Methods Formation of bonds to transition and inner transition metals Book Review: