Alkene Polymerization Reactions with Transition Metal Catalysts

Alkene Polymerization Reactions with Transition Metal Catalysts
Author: Yury Kissin
Publsiher: Elsevier
Total Pages: 495
Release: 2008-03-10
ISBN 10: 9780080557991
ISBN 13: 0080557996
Language: EN, FR, DE, ES & NL

Alkene Polymerization Reactions with Transition Metal Catalysts Book Review:

During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent several major changes: 1. The list of commercial heterogeneous Ziegler-Natta catalysts for the synthesis of polyethylene and stereoregular polyolefins was completely renewed affording an unprecedented degree of control over the polymer structure. 2. Research devoted to metallocene and other soluble transition-metal catalysis has vastly expanded and has shifted toward complexes of transition metals with multidentate ligands. 3. Recent developments in gel permeation chromatography, temperature-rising fractionation, and crystallization fractionation provided the first reliable information about differences between various active centers in transition-metal catalysts. 4. A rapid development of high-resolution 13C NMR spectroscopy resulted in greatly expanded understanding of the chemical and steric features of polyolefins and alkene copolymers. These developments require a new review of all aspects of alkene polymerization reactions with transition-metal catalysts. The first chapter in the book is an introductory text for researchers who are entering the field. It describes the basic principles of polymerization reactions with transition-metal catalysts, the types of catalysts, and commercially manufactured polyolefins. The next chapter addresses the principal issue of alkene polymerization catalysis: the existence of catalyst systems with single and multiple types of active centers. The subsequent chapters are devoted to chemistry and stereochemistry of elemental reaction steps, structures of catalyst precursors and reactions leading to the formation of active centers, kinetics of polymerization reactions, and their mechanisms. The book describes the latest commercial polymerization catalysts for the synthesis of polyethylenes and polypropylene The book provides a detailed description of the multi-center nature of commercial Ziegler-Natta catalysts. The book devotes specialized chapters to the most important aspects of transition metal polymerization catalysts: the reactions leading to the formation of active centers, the chemistry and stereochemistry of elemental polymerization steps, reaction kinetics, and the polymerization mechanism. The book contains an introductory chapter for researchers who are entering the field of polymerization catalysis. It describes the basic principles of polymerization reactions with transition-metal catalysts and the types of commercially manufactured polyolefins and copolymers The book contains over 2000 references, the most recent up to end of 2006.

Alkene Polymerization Reactions with Transition Metal Catalysts

Alkene Polymerization Reactions with Transition Metal Catalysts
Author: Y. V. Kissin
Publsiher: Elsevier Science & Technology
Total Pages: 592
Release: 2008
ISBN 10: 9781435628755
ISBN 13: 1435628756
Language: EN, FR, DE, ES & NL

Alkene Polymerization Reactions with Transition Metal Catalysts Book Review:

During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent several major changes: 1. The list of commercial heterogeneous Ziegler-Natta catalysts for the synthesis of polyethylene and stereoregular polyolefins was completely renewed affording an unprecedented degree of control over the polymer structure. 2. Research devoted to metallocene and other soluble transition-metal catalysis has vastly expanded and has shifted toward complexes of transition metals with multidentate ligands. 3. Recent developments in gel permeation chromatography, temperature-rising fractionation, and crystallization fractionation provided the first reliable information about differences between various active centers in transition-metal catalysts. 4. A rapid development of high-resolution 13C NMR spectroscopy resulted in greatly expanded understanding of the chemical and steric features of polyolefins and alkene copolymers. These developments require a new review of all aspects of alkene polymerization reactions with transition-metal catalysts. The first chapter in the book is an introductory text for researchers who are entering the field. It describes the basic principles of polymerization reactions with transition-metal catalysts, the types of catalysts, and commercially manufactured polyolefins. The next chapter addresses the principal issue of alkene polymerization catalysis: the existence of catalyst systems with single and multiple types of active centers. The subsequent chapters are devoted to chemistry and stereochemistry of elemental reaction steps, structures of catalyst precursors and reactions leading to the formation of active centers, kinetics of polymerization reactions, and their mechanisms. The book describes the latest commercial polymerization catalysts for the synthesis of polyethylenes and polypropylene The book provides a detailed description of the multi-center nature of commercial Ziegler-Natta catalysts. The book devotes specialized chapters to the most important aspects of transition metal polymerization catalysts: the reactions leading to the formation of active centers, the chemistry and stereochemistry of elemental polymerization steps, reaction kinetics, and the polymerization mechanism. The book contains an introductory chapter for researchers who are entering the field of polymerization catalysis. It describes the basic principles of polymerization reactions with transition-metal catalysts and the types of commercially manufactured polyolefins and copolymers The book contains over 2000 references, the most recent up to end of 2006.

Alkene Polymerization Reactions with Transition Metal Catalysts Studies in Surface Science and Catalysis

Alkene Polymerization Reactions with Transition Metal Catalysts  Studies in Surface Science and Catalysis
Author: Kissin YV.
Publsiher: Unknown
Total Pages: 329
Release: 2008
ISBN 10:
ISBN 13: OCLC:985741281
Language: EN, FR, DE, ES & NL

Alkene Polymerization Reactions with Transition Metal Catalysts Studies in Surface Science and Catalysis Book Review:

Handbook of Transition Metal Polymerization Catalysts

Handbook of Transition Metal Polymerization Catalysts
Author: Ray Hoff
Publsiher: John Wiley & Sons
Total Pages: 768
Release: 2018-04-20
ISBN 10: 1119242150
ISBN 13: 9781119242154
Language: EN, FR, DE, ES & NL

Handbook of Transition Metal Polymerization Catalysts Book Review:

Including recent advances and historically important catalysts, this book overviews methods for developing and applying polymerization catalysts – dealing with polymerization catalysts that afford commercially acceptable high yields of polymer with respect to catalyst mass or productivity. • Contains the valuable data needed to reproduce syntheses or use the catalyst for new applications • Offers a guide to the design and synthesis of catalysts, and their applications in synthesis of polymers • Includes the information essential for choosing the appropriate reactions to maximize yield of polymer synthesized • Presents new chapters on vanadium catalysts, Ziegler catalysts, laboratory homopolymerization, and copolymerization

Transition Metals and Organometallics as Catalysts for Olefin Polymerization

Transition Metals and Organometallics as Catalysts for Olefin Polymerization
Author: Walter Kaminsky,Hansjörg Sinn
Publsiher: Springer Science & Business Media
Total Pages: 442
Release: 2012-12-06
ISBN 10: 3642832768
ISBN 13: 9783642832765
Language: EN, FR, DE, ES & NL

Transition Metals and Organometallics as Catalysts for Olefin Polymerization Book Review:

More than 30 years after the discovery of transition metals and organometal lics as catalysts for olefin polymerization these catalysts did not have lost their fascination. Since 1953 when Karl Ziegler has discovered the catalytic polymerization of ethylene leading to plastically formable polymers which are mechanically stable up to temperatures of about 100°C, synthetic polymers and rubbers have made their way right into private houses. This discovery has been a main impetus for the fast growing production of plastics. The stereoselective poly merization of propylene and other long-chain a-olefins first detected by Giulio Natta leads to an even broadened field of applications. Another enforcing factor were the developments of Standard Oil of Indiana and Phillipps Petroleum Company who engaged in the polymerization of a-olefins supported molybdenum, cobalt and later on chromium catalysts which clearly indicates the wide variety of suitable systems. This kind of research acknowledged merit when in 1963 the Nobel prize of chemistry was awarded to Ziegler and Natta. Although to a great extent there is a technical application for these catalysts, up to now the nature of the active centres and many reaction mechanisms are not completely known.

Direct Observation of Zirconocene catalyzed Alkene Polymerization Via NMR and the Role of an Aluminum Alkyl During Ploymerization

Direct Observation of Zirconocene catalyzed Alkene Polymerization Via NMR and the Role of an Aluminum Alkyl During Ploymerization
Author: Janice Hall Tomasik
Publsiher: Unknown
Total Pages: 248
Release: 2007
ISBN 10:
ISBN 13: WISC:89101162097
Language: EN, FR, DE, ES & NL

Direct Observation of Zirconocene catalyzed Alkene Polymerization Via NMR and the Role of an Aluminum Alkyl During Ploymerization Book Review:

Transition Metal Catalysis in Macromolecular Design

Transition Metal Catalysis in Macromolecular Design
Author: Lisa Saunders Boffa,Bruce M. Novak
Publsiher: Amer Chemical Society
Total Pages: 299
Release: 2000
ISBN 10:
ISBN 13: UOM:39015050186801
Language: EN, FR, DE, ES & NL

Transition Metal Catalysis in Macromolecular Design Book Review:

Metal-mediated polymerization is fast becoming an essential tool for the fine control of macromolecular architecture. Advanced Catalysis demonstrates how the field of transition metal-catalyzed polymer syntheses has moved beyond the simple use of single-site catalysts to new applications and "advanced" techniques of architectural control. This book defines and presents "next generation" techniques and trends for polymer architecture control for an immediate grasp on the future of this exciting field.

Transition Metal Catalyzed Polymerizations

Transition Metal Catalyzed Polymerizations
Author: Roderic P. Quirk
Publsiher: Taylor & Francis
Total Pages: 886
Release: 1983
ISBN 10: 9783718601431
ISBN 13: 3718601435
Language: EN, FR, DE, ES & NL

Transition Metal Catalyzed Polymerizations Book Review:

Proceedings of the National Academy of Sciences of the United States of America

Proceedings of the National Academy of Sciences of the United States of America
Author: National Academy of Sciences (U.S.)
Publsiher: Unknown
Total Pages: 329
Release: 2006
ISBN 10:
ISBN 13: WISC:89099183980
Language: EN, FR, DE, ES & NL

Proceedings of the National Academy of Sciences of the United States of America Book Review:

Olefin Polymerization

Olefin Polymerization
Author: Walter Kaminsky
Publsiher: Wiley-VCH
Total Pages: 500
Release: 2006-08-18
ISBN 10: 9783527317424
ISBN 13: 3527317422
Language: EN, FR, DE, ES & NL

Olefin Polymerization Book Review:

With an enormous velocity, olefin polymerization has expanded to one of the most significant fields in polymers since the first industrial use about 50 years ago. In 2005, 100 million tons of polyolefins were produced - the biggest part was catalyzed by metallorganic compounds. The Hamburg Macromolecular Symposium 2005 with the title "Olefin Polymerization" involved topics such as new catalysts and cocatalysts, kinetics, mechanism and polymer reaction engineering, synthesis of special polymers, and characterization of polyolefins. The conference combined scientists from different disciplines to discuss latest research results of polymers and to offer each other the possibility of cooperation. This is reflected in this volume, which contains invited lectures and selected posters presented at the symposium.

Solution Structures of Two Homogeneous Early Transition metal Olefin Polymerization Catalysts

Solution Structures of Two Homogeneous  Early Transition metal  Olefin Polymerization Catalysts
Author: John Monteval Wright
Publsiher: Unknown
Total Pages: 398
Release: 1997
ISBN 10:
ISBN 13: WISC:89066543455
Language: EN, FR, DE, ES & NL

Solution Structures of Two Homogeneous Early Transition metal Olefin Polymerization Catalysts Book Review:

Synthesis and Development of Bidentate 3 4 diazaphospholanes for Metal catalyzed Reactions

Synthesis and Development of Bidentate 3 4 diazaphospholanes for Metal catalyzed Reactions
Author: Brian G. Hashiguchi
Publsiher: Unknown
Total Pages: 287
Release: 2008
ISBN 10:
ISBN 13: WISC:89101822385
Language: EN, FR, DE, ES & NL

Synthesis and Development of Bidentate 3 4 diazaphospholanes for Metal catalyzed Reactions Book Review:

Transition Metal Catalyzed Polymerizations

Transition Metal Catalyzed Polymerizations
Author: Roderic P. Quirk,Raymond E. Hoff,University of Akron. Institute of Polymer Science,Edison Polymer Innovation Corporation
Publsiher: CUP Archive
Total Pages: 868
Release: 1988
ISBN 10: 9780521332897
ISBN 13: 0521332893
Language: EN, FR, DE, ES & NL

Transition Metal Catalyzed Polymerizations Book Review:

This volume contains the proceedings of the Second International Symposium on Transition Metal Catalyzed Polymerizations held in 1986. The papers provide a broad-based perspective covering recent scientific and technological advances in Ziegler-Natta and metathesis polymerization, including olefin, diene, and acetylene polymerization, and copolymerization. The emphasis on reaction kinetics of polymerizations in different reagent and catalyst environments makes this volume of interest to both academic and industrial researchers.

Comprehensive Organometallic Chemistry III

Comprehensive Organometallic Chemistry III
Author: Robert Crabtree
Publsiher: Unknown
Total Pages: 9000
Release: 2007
ISBN 10:
ISBN 13: STANFORD:36105122424513
Language: EN, FR, DE, ES & NL

Comprehensive Organometallic Chemistry III Book Review:

Comprehensive Organometallic Chemistry, (COMC-III), Third Edition, 13 Volume Set is aimed at the specialist and non-specialist alike. It covers the major developments in the field in a carefully presented way with extensive cross-references. COMC-III provides a clear and comprehensive overview of developments since 1993 and attempts to predict trends in the field over the next ten years. Applications of organometallic chemistry continue to expand and this has been reflected by the significant increase in the number of volumes devoted to applications in COMC-III. Organic chemists have edited the volumes on organometallic chemistry towards organic synthesis - this is now organized by reaction type so as to be readily accessible to the organic community. Like its predecessors, COMC (1982) and COMC-II (1995), this new work is the essential reference text for any chemist or technologist who needs to use or apply organometallic compounds. Also available online via ScienceDirect (2006) - featuring extensive browsing, searching, and internal cross-referencing between articles in the work, plus dynamic linking to journal articles and abstract databases, making navigation flexible and easy. For more information, pricing options and availability visit www.info.sciencedirect.com. Presents a comprehensive overview of the major developments in the field since 1993 providing general and significant insights Highlights the expansion of applications in organometallic chemistry with a strong organic synthesis focus Provides a structured first point of entry to the key literature and background material for those planning research, teaching and writing about the area

Step growth Polymers for High performance Materials

Step growth Polymers for High performance Materials
Author: James L. Hedrick,American Chemical Society,Jeff W. Labadie,American Chemical Society. Division of Polymer Chemistry,American Chemical Society. Meeting,Calif.) American Chemical Society Meeting 1995 (Anaheim
Publsiher: Amer Chemical Society
Total Pages: 469
Release: 1996
ISBN 10:
ISBN 13: UOM:39015037703306
Language: EN, FR, DE, ES & NL

Step growth Polymers for High performance Materials Book Review:

Presents the latest work in transition metal catalyzed polymerization, dendritic and hyperbranched systems, poly(aryl ether) synthesis, polyimides, and high-temperature polymers. Describes recent research on commercially important polymers based on step-growth polymerization. Includes well-referenced overview articles that review step-growth polymerization and indicate how individual research papers have impacted the field.

Kinetics and Thermodynamics of D0 yttrocene alkyl alkene Complexes I Reaction Rates of Alkenes with Cp 2YH THF II

Kinetics and Thermodynamics of D0 yttrocene alkyl alkene Complexes   I    Reaction Rates of Alkenes with Cp 2YH THF    II
Author: Jennifer Fisher Klein
Publsiher: Unknown
Total Pages: 490
Release: 1999
ISBN 10:
ISBN 13: WISC:89072064330
Language: EN, FR, DE, ES & NL

Kinetics and Thermodynamics of D0 yttrocene alkyl alkene Complexes I Reaction Rates of Alkenes with Cp 2YH THF II Book Review:

Early Main Group Metal Catalysis

Early Main Group Metal Catalysis
Author: Sjoerd Harder
Publsiher: John Wiley & Sons
Total Pages: 400
Release: 2020-02-03
ISBN 10: 3527344489
ISBN 13: 9783527344482
Language: EN, FR, DE, ES & NL

Early Main Group Metal Catalysis Book Review:

Early Main Group Metal Catalysis gives a comprehensive overview of catalytic reactions in the presence of group 1 and group 2 metals. Chapters are ordered to reaction type, contain educational elements and deal with concepts illustrated by examples that cover the main developments. After a short introduction on polar organometallic chemistry and synthesis of early main group metal complexes, a variety of catalytic reactions are described, e.g. polymerization of alkenes, hydroamination and phosphination reactions, hydrosilylation, hydroboration and hydrogenation catalysis, as well as enantioselective and Lewis-acid catalysis. The book addresses organic chemists and researchers in industry interested in the state-of-the-art and new possibilities of early main group metal catalysis as well as newcomers to the field. Written by a team of leaders in the field, it is a very welcome addition to the area of main group metal chemistry, and to the field of catalysis.

Polymer Properties

Polymer Properties
Author: Geoffrey Allen,Colin Booth,J. C. Bevington,Colin Price
Publsiher: Pergamon
Total Pages: 798
Release: 1989
ISBN 10: 9780080362069
ISBN 13: 0080362060
Language: EN, FR, DE, ES & NL

Polymer Properties Book Review:

Volume 2.

Transition Metal catalyzed Reactions of Alkynes

Transition Metal catalyzed Reactions of Alkynes
Author: Cheol Keun Chung
Publsiher: Unknown
Total Pages: 738
Release: 2006
ISBN 10:
ISBN 13: STANFORD:36105127121817
Language: EN, FR, DE, ES & NL

Transition Metal catalyzed Reactions of Alkynes Book Review:

Homogeneous Catalysis by Metal Complexes Activation of alkenes and alkynes

Homogeneous Catalysis by Metal Complexes  Activation of alkenes and alkynes
Author: M. M. Taqui Khan,Arthur Earl Martell
Publsiher: Unknown
Total Pages: 329
Release: 1974
ISBN 10:
ISBN 13: UOM:39076006404128
Language: EN, FR, DE, ES & NL

Homogeneous Catalysis by Metal Complexes Activation of alkenes and alkynes Book Review: